Orgo Reactants

LDA

E2

Concen. HCl + Heat

Sn1

HCl

Addition (most sub) + epoxide opener

Concen. H2SO4 / H3PO4 + Heat

E1 alcohol eliminator

NaH + LG

Epoxide creator

A) NaH B) BrCH2CH3

Carbon chain addition to Oxygen

Excess NaNH2 + Heat

Double E2

A) NaNH2 B)…

Deprotonater

Br2

Addition (opp. stereochem.)

Br2, H2O

Addition (Br least sub., OH most sub.)

A) Hg(OAc)2, H2O B)NaBH4

Addition (OH to most sub carbon)

Grignard

Epoxide opener (least stable carbon), ketone breaker to add carbon chain

LiAlH4

Alcohol, Amine, Alkane creator

A) NaBH4 B) H+

Alcohol creator

mCPBA

Makes epoxides (from alkenes)

Mg, Li

Grignard creators from LG - R

A) BH3 B)HOO-

Adds OH to Alkenes on Least Sub carbon

A) O3 B) DMS

Adds oxygen to double bond ends

A) OsO4 / KMnO4 B)NaOH, H2O

Addition of 2 OH groups to alkene (same stereochem.)

CH2N2

Alkene to “carbon epoxide”

H+, H2O + heat / HgSO4, H2SO4, H2O

Alkyne to Ketone

A) Hb(Sia)2 B)HOO-

Alkyne to Aldehyde

Br2 + light

Br addition to most sub. carbon

Cl2 + Light

Non-regiospecific Cl addition

HBr, ROOR + Light

Addition (Br on least sub. of double)

H2Pd

Alkyne, Alkene to Alkane

H2, Lindlars

Alkyne to Z Alkene

Li, NH3 (l)

Alkyne to E Alkene

PositiveMoleculeCN, H2O

Sn2 (C - - -N)