Kinetic Theory of Gases

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Ideal gases

ideal gas equation

AN IDEAL GAS”

  • Particles are in constant and random motion. 

  • All collisions between particles are elastic

  • The volume of gas particles is negligible compared to the volume of container

  • There are no intermolecular forces between gas particles

  • The kinetic energy of gas particles is directly proportional to the absolute temperature of the gas

pV = nRT


p = pressure in pascals (Pa)
T = temperature in kelvins (K)
V = volume in cubic meters (m3)
n = the amount of gas (mol)
R = gas constant (8.3145 (J)/(mol × K))

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Avogadro’s law

Equal volumes of gases contain the same number of particles at the same temperature and pressure!

n =  Amount of substance (mol)
V = Volume of gas (l = dm3)
Vm = Molar volume of a gas (22.7 L) in STP

STP = Standard Temperature and Pressure

Temperature 273.15 K = 0 oC

Absolute pressure of exactly 1 bar = 100 000 Pa

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Combined gas law

p1 = initial pressure p2 = final pressure
T1 = initial temperature T2 = final temperature
V1 = initial volume V2 = final volume

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