Organic Chemistry 2 - Exam 3

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79 Terms

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<p></p>

<p></p>

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<p><mark data-color="purple" style="background-color: purple; color: inherit">Draw the Product</mark></p>

Draw the Product

Reagent from halide to figure

<p>Reagent from halide to figure</p>

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<p><mark data-color="purple" style="background-color: purple; color: inherit">Draw the product</mark></p>

Draw the product

reagent from cyano to figure

<p>reagent from cyano to figure</p>

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Draw the Mechanism of a Carboxylation of a Grignard reagent with CO2

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<p><mark data-color="purple" style="background-color: purple; color: inherit">Reagent as Na2Cr2O7, H2SO4, H2O</mark></p>

Reagent as Na2Cr2O7, H2SO4, H2O

What is the reagent

<p>What is the reagent</p>

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<p><mark data-color="purple" style="background-color: purple; color: inherit">Draw the Product</mark></p>

Draw the Product

Carboxylic to primary alcohol

<p>Carboxylic to primary alcohol</p>

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<p><mark data-color="purple" style="background-color: purple; color: inherit">Draw the Product</mark></p>

Draw the Product

Selective version carboxylic acid to primary alcohol

<p>Selective version carboxylic acid to primary alcohol</p>

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What is the Nucleophilic Acyl Substitution Mechanism

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<p>Mechanism</p>

Mechanism

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<p><mark data-color="yellow" style="background-color: yellow; color: inherit">Mechanism</mark></p>

Mechanism

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<p><mark data-color="yellow" style="background-color: yellow; color: inherit">Mechanism</mark></p>

Mechanism

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<p>Mechanism</p>

Mechanism

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<p>Fischer Esterification Mechanism</p>

Fischer Esterification Mechanism

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<p>Mechanism</p>

Mechanism

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<p>Mechamism</p>

Mechamism

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<p>Mechanism</p>

Mechanism

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<p>Mechanism</p>

Mechanism

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<p>mMechanism</p>

mMechanism

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Reagent: Carboxylic to Ester

Acidic conditions & ROH

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Reagent: Ester to Carboxylic Acid

Acidic Conditions plus water

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Reagent: Carboxylic Acid to Anhydride

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Reagent: Anhydride to Carboxylic Acid

H2O

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Reagent: Carboxylic Acid to acyl halide

SOCl2

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Reagent: Acyl Halide to Carboxylic Acid

H2O & Pyridine

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Reagent: Amide to Carboxylic Acid

Acidic Conditions + Water + Heat

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Reagent: Cyano to Carboxylic Acid

Acidic + water + heat

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Reagent: Primary Alcohol to carboxylic acid

Na2Cr2O7, H2SO4, H2O

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Reagent:Carboxylic Acid to Primary Alcohol

LAH
H2O

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Reagent: Acyl Halide to Primary Alcohol

LAH
H2O

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Reagent: Acyl Halide to Anhydride

RCO2H
Pyridine

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Reagent: Anhydride to Ester

ROH

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Reagent: Ester to Amide

NH3

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Reagent: Amide to Cyano Group

SOCl2

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Reagent: Acyl Halide to Primary Alcohol

LAH
H2O

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Reagent: Alcyl Halide to Aldehyde

LiAl(OR)3H
H2O

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Reagent: Ester to Aldehyde

DIBAH
Water

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Reagent: Ester to Primary Alcohol

xs LAH
H2O

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Reagent: Acyl Halide to Amide

xs NH3

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Reagent: Acyl Halide to Ester

ROH, pyridine

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Reagent: Amide to Amine

xs LAH
Water

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Reagent: Cyano group to amine

xs LAH
H2O

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Acidic Tautomerization

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Basic Tautomerization

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Enol Formation Mechanism

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<p>Mechanism</p>

Mechanism

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<p>Mechanism</p>

Mechanism

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Adol Addition Mechanism

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<p>Draw all the products</p>

Draw all the products

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Claisen Condensation Mechanism

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Base to make enolate & ketone

NaOH or NaOEt

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Base to make ONLY the enolate

NaH or LDA

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