Element
cannot be made simpler, building block of matter. Includes diatomics, atoms, and even polyatomic
Compound
Pure substances that can be broken down by chemical means ie. NaCl
Atoms
Neutral particles
molecules
Smallest physical unit, always neutral eg. a molecule of H2O
elements of a chemical formula
subscripts (number of atoms), superscript (charge), coefficient (# compounds), balanced
accurate
results close to the actual number
precise
results close to each other
Physical properties
appearance, smell, feel, melting point, density, etc
chemical properties
how things react ex. Mg burns in air
wtf is a barometer or a manometer
google it bitch
Methods of separation
decanting, filtration, distillation, evaporation
diatomics
H O N F I Cl Br
Ammonium
NH4 +
Hydroxide
OH -
Nitrate
NO3 -
Sulfate
SO4 2-
Carbonate
CO3 2-
Phosphate
PO4 3-
Diatomic tool
NICK the BABY CAMEL ate and INCH CLAM and CREPES for SUPPER in PHOENIX
Practice naming
don’t procrastinate
What is the number of protons
constant, atomic #
How to find neutrons
Mass-Protons/atomic #
Single replacement reaction
compound breaks apart and combines with the other reactant which is typically an element
Double replacement reaction
Both reactants break apart and recombine into two new parts
Synthesis/combination reaction
Several reactants combine to form a single product
decomposition reaction
a compound breaks down bc of a chemical change
Combustion reaction
tends to make H2O+CO2, reaction w/ O2 that produces light and heat
Group I solubility
soluble
NO3 - solubility
soluble
NH4+
soluble
Famous Precipitates
BaSO4 (white), PbI2 (bright yellow), AgCl, AgBr, AgI (white to pale yellow)
Precipitate Reaction
AB + XY = XB + AY (two ionics make at least one non soluble product)
Which are almost always (always when not with an always soluble) insoluble?
OH- (hydroxide), CO3 2- (carbonate), C2O4 2- (oxalate), PO4 3- (phosphate), "heavy metals"
electron configuration
1s2 2s2 2p5 etc (in order spdf)
What are orbital diagrams
the up down arrow ones
Coulomb's law
the force of attraction or repulsion between two charged particles is directly proportional to the product of the charges and inversely proportional to the distance between them. F = (kq1q2)/dˆ2
As an electron moves away from the nucleus it's potential energy...
..increases
what is special about transition metal ions?
they lose electrons from the s sublevel before d
isometric
same electron configuration (K+, Cl-, S2-, Ar)
periodic groups are...
...columns, # of electrons in outer shell
periodic periods are...
...rows, # of shells
transition element properties
conductive, malleable, for ions with variety of positive charges, act as good catalysts, often form colored compounds, form variety of alloys
valence electrons
outermost electron ring (highest energy level)
core electrons
\n all non valence electrons
effective strength formula
proton # - # core electrons = strength of + on valence e-
electronegativity/electron affinity
how much an element will attract electrons. increases (+ charge increases) across the periodic table, and decreases (greater atomic radii) descending
ionization energy (IE)
energy required to remove an electron. increases across (+ charge increases) and decreases descending periodic table (more barriers)
Evaporation is endothermic or exothermic
endothermic, need to GIVE it heat
cation
positive, metal
anion
negative, non-metal
Order of IMFs (least to greatest)
Disperson, dipole-dipole, hydrogen
Trigonal pyramidal
4 e- pairs, 3 bonds, 1 lone pair
Tetrahedral
4 e- pairs, all bonds
Octahedral
6 e- pairs, all bonds, x,y,z
Trigonal planar
3 e- pairs, all bonds, flat
Linear
2 e- pairs, all bonds, a line
Bent
4 e- pairs, 2 bonds, 2 lone pairs, angle
Water's normal boiling point is 100˚C, why can water evaporate at 20˚C?
Because of random velocities of water molecules causing some to have a high enough kinetic energy to escape from the surface.
What havens to water vapor pressure in a container with ice melting at room temp?
Increases rapidly, then more slowly until reaching equilibrium
What happens to the rate of condensation?
Increases until it equals the rate of evaporation and then remains constant.
What are the affects of temp, IMFs, and molar mass on the vapor pressure of a substance?
Vapor pressure increases with an increase in temp and a decrease in strength of IMFs and molar mass.
When, in general, does a liquid begin to boil?
\n When the vapor pressure equals the outside pressure
Why does ice have a lower density than water>
than water>
Because of the crystal structure formed by hydrogen bonds and its open structure.
hydrogen bonds occur when hydrogen is bonded to which elements
F, O, N
kinetic molecular theory
gas molecules are in constant random motion, when they collide energy is not lost, do not attract each other, far apart, same temp, same average kinetic energy
kinetic energy formula
KE=1/2mvˆ 2
pressure and force formula
p=f/a
Formula for pressure, volume, and temp
pv/t = pv/t
Dalton's law of partial pressures
Since gas pressure depends on # of molecules not their mass or size, it is easy to see that each gas in a mixture contributes pressure according to the number of molecules present.
Graham's Law
small particles diffuse faster
˚ C to K
+273
atm to mmHg
atm x 760
How do gasses exert pressure?
Tiny molecules colliding with every pinhead-sized area of any surface. # of collisions is identical, forces add up for exert a force on the whole surface, creating a uniform "pressure".
Which is larger: proportional more collisions or harder collisions
samsies
mole to liter (for gasses)
1 mol = 22.4L
molar mass
g/mol
particles / mol
6.02x10ˆ 23
Relative atomic mass
average atomic mass of all isotopes based on how common they are: (mass(%)+mass(%))/100
percent composition by mass
mass/total mass
density=
m/v
molarity
mass of solute per solution: moles of solute/liters
Dilution rule
concentration 1(volume 1) = concentration 2(volume 2)
Ideal gas law
PV = nRT
When will something produce a smell
when it is polar
When something has a charge, the polarity is…
Not applicable
manometer gas pressure shit
if gas is lower than outside: atmosphere pressure - height (mm) = gas pressure (mmHg)
If gas is greater than out side side: atmosphere pressure + height (mm) = gas pressure (mmHg)
percent error
(|accepted-measured| x 100) / accepted
is phase change a physical or chemical change
physical