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What dimension does Lewis structures describe connectivity in
2D
What geometries do real molecules have
3D
What can the 3D orientation of atoms have dramatic influence on
chemical properties of a molecule
What are molecules formed from
covalently bonded atoms
What two things does Covalent’s bonds optimal lengths allow
balance the penalty of nuclear repulsion and the benefit of sharing electrons
What do molecules with three or more atoms have
multiple covalent bonds
What are these bonds called
pairs of electrons
What do molecules adopt shapes to minimize
minimize repulsion of electrons, minimizing energy
True or false. Compounds with the same structure (connectivity) can have vastly different properties due to differences in shape (3-D)
True
What does VSEPR Theory stand for
Valence Shell Electron Pair Repulsion Theory
What is the simple premise of the VSEPR Theory. What does this represent
bonds and lone pairs centered on an atom take on an arrangement that maximizes the separation between them.
represents an energy minimizing position of the groups
How many electron group arrangements are there
5
What are arrangements based on
the number of electron regions around a central atom
What can be found under each arrangement
one or more molecular shapes that the central atom adopts based on the positions of the bonded nuclei
What can electron regions be
bonding pairs or lone pairs
How many regions do single, double, and triple bonds count as
one region
What is molecular geometry governed by
positions of nuclei about the central atom
What do AXnEm designations assigned to molecules determine
molecular shape
What does Xn represent
bonding group (n is the number of these groups)
What does Em represent
lone pairs (m is the number of these groups)
True or false. X is any bonding group, the type of bonded atom does not matter, only the number of bonded atoms
True
What is the Geometry of AX2
Linear
What is the Geometry of AX2E
Bent
What is the Geometry of AX3
Trigonal planar
What is the Geometry of AX4
Tetrahedral
What is the Geometry of AX3E
Trigonal pyramidal
What is the Geometry of AX2E2
Bent