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stereoisomers
same molecular formula + connectivity, different spatial arrangements
constitutional isomers
same molecular formula, different connectivity
chiral
no plane of symmetry + nonsuperimposable
chirality center
Carbon atom bonded to four different groups
achiral
plane of symmetry + superimposable
R
clockwise
S
counterclockwise
enantiomers
nonsuperimposable mirror image
diastereomers
nonsuperimposable + non mirror image