Free Radical Halogenation Reactions

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Last updated 7:51 PM on 8/13/26
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10 Terms

1
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What reaction is this?

Free radical halogenation using Bromine

2
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What does the free radical halogenation using bromine do?

Attack the most substituted carbon

Highly selective

Replaces hydrogen at the most stable, highly substituted carbon

(tertiary > secondary > primary)

Forms a bromoalkane

3
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What reaction is this?

Free radical halogenation using chlorine

4
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What does this reaction do?

Does the same as the bromine version

Less selective tho

Reaction is fast

Chlorine radicals are very reactive and not very selective

5
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Which is faster; free radical halogenation of bromine or chlorine?

Free radical halogenation of chlorine

6
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What reaction is this?

Allylic/benzylic bromination

7
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What does an allylic/benzylic bromination reaction do?

Replaces a specific hydrogen atom with a bromine atom on a carbon next to a double bond (allylic position) or next to a benzene ring (benzylic position)

8
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What reaction uses these reactants?

Free radical halogenation using bromine

9
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What reaction uses these reactants?

Free radical halogenation using chlorine

10
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What reaction uses these reactants?

Allylic/Benzyling bromination