Chemistry IGCSE

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93 Terms

1
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Order of fractions in refining petroleum (top to bottom):

  • refinery gas

  • gasoline

  • naphtha

  • kerosene

  • diesel oil

  • fuel oil

  • lubricating fraction

  • bitumen

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Refinery gas use:

bottled gas for heating and cooking

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Gasoline uses:

petrol for cars

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Naphtha uses:

making chemicals and plastics

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Kerosene uses:

fuel for aeroplanes, oil stoves and oil lamps

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Diesel oil uses:

fuel for diesel engines

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Fuel oil uses:

power stations, ships, home heating systems

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Lubricating fraction uses:

lubricants for car engines, machinery, waxes and polishes

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Bitumen uses:

making roads, covering roofs

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Cracking alkanes:

breaks non-useful long chain alkanes to smaller alkanes and at least one alkene

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Cracking alkanes process:

  • vaporised alkanes are passed over a catalyst

  • requires 600-700°C

  • requires silica or alumina/zeolite catalysts

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Identification of alkenes:

bromine water goes from orange to colourless thanks to an addition reaction

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Hydrogenation reactions:

  • alkene + hydrogen —> alkane

  • requires a nickel catalyst

  • requires 150°C

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Hydration reaction:

  • alkene + steam —> alcohol

  • requires 300°C

  • requires 60-70 atm of pressure

  • requires a phosphoric acid catalyst

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Combustion of alkanes:

alkane + oxygen —> carbon dioxide + water (+ heat)

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Substitution reaction between alkanes and chlorine:

  • alkane + chlorine gas —> hydrogen chloride + chloroalkanes

  • requires UV light (photochemical reaction)

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Polymerisation of alkenes requires:

  • heat

  • pressure

  • catalyst

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Anhydrous copper (II) sulfate colour:

white

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Hydrated copper (II) sulfate colour:

blue

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Anhydrous cobalt (II) chloride colour:

blue

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Hydrated cobalt (II) chloride colour:

pink

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Source of nitrogen for the Haber process:

air

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Haber process:

process to make fixed nitrogen

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Source of hydrogen for Haber process:

methane

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Typical conditions of the Haber process:

450°C, 200 atm, iron catalyst

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Contact process:

process to produce sulfuric acid

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Source of sulfur dioxide in Contact process:

burning sulfur, roasting sulfide ores

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Source of oxygen for Contact process:

air

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Typical conditions for the conversion of sulfur dioxide to trioxide in the Contact process:

450°C, 2 atm, vanadium oxide catalyst

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Acidified KMnO4 colour changes

purple to colourless when mixed with a reducing agent

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Aqueous Potassium iodide colour changes:

colourless to reddish-brown when mixed with an oxidising agent

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Catalytic converter catalyst

platinum and rhodium

33
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Avogadro constant (number of particles per mol)

6.02×10²³

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Electrolysis of molten lead(II) bromide

anode: bromine (brown gas)

cathode: lead (dark grey metal coat)

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Electrolysis of concentrated aq. sodium chloride (brine)

anode: chlorine (green bubbles)

cathode: hydrogen bubbles

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Electrolysis of dilute sulfuric acid:

anode: oxygen bubbles

cathode: hydrogen bubbles

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Electrolysis of aq copper (II) sulfate with non-copper electrodes:

anode: oxygen bubbles

cathode: copper (red-brown metal coating)

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Electrolysis of aq copper (II) sulfate with copper electrode:

anode: oxygen bubbles + electrode shrinks

cathode: electrode gets bigger

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Solubility of sodium salts:

all soluble

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Solubility of potassium salts:

all soluble

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Solubility of ammonium salts:

all soluble

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Solubility of nitrate salts:

all soluble

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Solubility of chloride salts:

all soluble except lead and silver

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Solubility of sulfate salts:

all soluble except barium, calcium and lead

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Solubility of carbonate salts:

all insoluble except potassium, ammonium and sodium

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Solubility of hydroxide salts

all insoluble except sodium, ammonium, potassium, and calcium (partially)

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CO3 2- test
Add dilute acid, CO2 bubbles
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Cl- test
Acidify with nitric acid, add silver nitrate. White precipitate formed (AgCl)
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I- test
Acidify with nitric acid, add silver nitrate. Yellow precipitate formed (AgI)
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Br- test
Acidify with nitric acid, add silver nitrate. Cream precipitate formed (AgBr)
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NO3- test
Add NaOH, add aluminium gently. Ammonia formed.
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SO4 2- test
Acidify, add barium nitrate. White precipitate (Barium Sulfate) forms
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SO3 2- test
Add dilute HCl, warm gently. SO2 produced.
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Al 3+ and aq NaOH
White precipitate. Clear solution. Soluble in excess.
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Al 3+ and aq NH3
White precipitate. Insoluble in excess.
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NH4 + and aq NaOH
Red brown precipitate, insoluble in excess
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Ca 2+ and aq. NaOH
White precipitate. Insoluble in excess
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Ca 2+ and aq. NH3
Nothing
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Cr 3+ and aq NaOH
Greenish precipitate, insoluble in excess.
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Cr 3+ and aq NH3
Greenish precipitate, insoluble in excess
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Cu 2+ and aq NaOH
Blue precipitate, insoluble in excess
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Cu 2+ and aq. NH3
Turquoise precipitate, dark blue solution in excess.
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Fe 2+ and aq. NaOH
Green precipitate in clear solution, insoluble in excess.
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Fe 2+ and aq. NH3
Greenish precipitate, insoluble in excess.
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Fe 3+ and aq. NaOH
Orange-brown precipitate, insoluble in excess
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Fe 3+ and aq. NH3
Orange-brown precipitate, insoluble in excess.
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Zn 2+ and aq. NaOH.
White precipitate, clear colourless solution, soluble in excess,
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Zn 2+ and aq. NH3
White precipitate, colourless solution in excess
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Ammonia test
Turns damp red litmus paper on top of container blue
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CO2 test
Limewater turns milky
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H2 test
Lit splint, squeaky pop
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O2 test
Glowing splint relights
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SO2 test
Turns acidified KMnO4 from purple to colourless
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Cl2 test
Bleaches damp litmus paper
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Li+ flame test
red
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Na+ flame test
yellow
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K+ flame test
lilac
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Ca 2+ flame test
red
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Ba 2+ flame test
green
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Cu 2+ flame test
blue-green
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Graphite structure

  • Allotrope of carbon

  • Each carbon atoms forms covalent bonds with 3 others, forming hexagons of strong bonds

  • The atoms each lose the fourth electron, which stays between layers and holds the layers together with weak electrostatic forces

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Diamond structure

  • Allotrope of carbon

  • Each carbon atom forms 4 covalent bonds with 4 other atoms

  • Forms a tetrahedron

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Silicon (IV) dioxide structure

  • Each silicon atom forms covalent bonds with 4 oxygen atoms, and each oxygen atom forms covalent bonds with 2 silicon atom

  • forms tetrahedron structure

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Flue gas desulfurisation

reacting sulfur dioxide in flue gas with calcium oxide to remove sulfur

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Relative mass of an electron

1/2000

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Top number in an atomic symbol

Mass number

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Bottom number in an atomic symbol

Proton number

88
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Properties of ionic compounds:

  • high melting and boiling point (strong intermolecular forces between oppositely charged ions)

  • conduct electricity when molten/aqueous

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Properties of covalent bonds:

  • strong intramolecular forces

  • weak intermolecular forces

  • low boiling and melting point

  • electrical insulator

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How do enzymes work?

provide a pathway that needs less activation energy

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Formula of hydrated copper sulfate:

CuSO4.5H2O

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Formula of hydrated cobalt chloride:

CoCl2.6H2O

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Flame colour vs alkane chain length:

Short chain: blue flame, little smoke

Long chain: yellow smoky flame