Precipitation reactions

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Last updated 7:08 PM on 9/7/26
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9 Terms

1
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What are precipitation reactions

Occurs when two aqueous solutions containing ions react to form an insoluble ionic solid, called a precipitate

2
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Precipitation colours

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3
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What happens when CoCl2, dissolves in water

  • A pale pink solution forms containing six co-ordinate complex ion [Co(H2O)6]2+

  • When [Co(H2O)6]2+ with excess HCl blue complex ion [CoCl4]2- forms

  • When [Co(H2O)6]2+ with NaOH blue green solid Co(OH)2


4
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How do Cu2+ ions react with NaOH

  • Blue solution reacts to form to form blue ppt copper (II) hydroxide which is insoluble in excess NaOH

  • Cu2+(aq) + 2OH⁻(aq) → Cu(OH)2(s)


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How do Fe2+ ions react with NaOH

  • Pale green solution reacts to form a pale green ppt of iron (II) hydroxide which is insoluble in excess NaOH but in air is oxidised to iron (III) and turns brown at its surface

  • Fe2+(aq) + 2OH⁻(aq) → Fe(OH)2(s)
    In air:
    Fe(OH)2(s) → Fe(OH)3(s)


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How do Fe3+ ions react with NaOH

  • Pale yellow solution reacts to form an orange brown ppt of iron (III) hydroxide which is insoluble in excess NaOH

  • Fe3+(aq) + 3OH⁻(aq) → Fe(OH)3(s)


7
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How do Mn2+ ions react with NaOH

  • Pale pink solution reacts to form a light brown ppt of manganese (II) hydroxide which darkens on standing in air and is insoluble in excess NaOH

  • Mn2+(aq) + 2OH⁻(aq) → Mn(OH)2(s)


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How do Cr3+ ions react with NaOH

  • Violet solution forms a grey-green ppt of chromium (III) hydroxide, this is soluble in excess NaOH and forms a dark green solution

  • Cr3+(aq) + 3OH⁻(aq) → Cr(OH)3(s)


    Cr(OH)3(s) + 3OH⁻(aq) → [Cr(OH)6]3+(aq)



9
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Transition metals precipitation reactions with ammonia

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