Ligands

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Last updated 12:03 AM on 4/20/23

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33 Terms

1

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oxalato

bidentate, C2O4, -2

2

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ethylenediamine

bidentate, “en”, 0

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carbonate

bidentate, CO3, -2

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diethylenetriamine

polydentate, 0

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ethylenediaminetetraacetate

polydentate, EDTA, -4

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naming

cation ligand(s) metal(ox#) anions

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1

mono

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2

di, bis

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3

tri, tris

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4

tetra, tetrakis

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5

penta

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6

hexa

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Cu

cuprate

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Fe

ferrate

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Cr

chromate

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Au

aurate

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Sn

stannate

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Co

cobaltate

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CN-

cyano

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NH3

ammine

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OH2

aqua

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CO

carbonyl

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NO2-

nitro

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only change ending on metals if

there isn’t an anion and there is a cation

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Br-

bromo

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Cl-

chloro

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F-

fluoro

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I-

iodo

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OH-

hydroxo

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weak ligands

high-spin, e- in each orbital before pairings

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strong ligands

low-spin, e- in bottom orbitals first

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paramagnetic

unpaired e-

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diamagnetic

all paired e-