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What is the Periodic Table?
A chart that organises the chemical elements
it helps chemists predict how elements will react in chemical reactions
and elements are arranged according to their properties
Who devised the first useful Periodic Table and when?
Dmitri Mendeleev
How did Mendeleev arrange the elements?
In order of increasing atomic mass
he called the vertical columns groups and the horizontal rows periods
What did Mendeleev do where no known element fitted?
He left gaps in his table and predicted the properties of several missing elements
What happened to Mendeleev's prediction of eka-silicon?
The element germanium was later discovered and its properties matched Mendeleev's predictions closely
How is the modern Periodic Table arranged?
In order of increasing proton number (atomic number)
it contains 118 known elements
Who showed that elements are better arranged by proton number than atomic mass?
Ernest Rutherford and Henry Moseley
What are periods?
The horizontal rows of the Periodic Table
What are groups?
The vertical columns of the Periodic Table
in traditional notation numbered Group I to Group VIII
What are metalloids?
Elements on the zig-zag line dividing metals and non-metals
they behave in some ways like metals and in other ways like non-metals
What is the trend across a period from left to right?
A gradual change from metal to non-metal
the number of electrons in the outer shell increases
structure changes from giant metallic
to giant covalent
Which elements are in Group I?
Lithium
General physical properties of Group I metals
Very reactive metals stored under oil
good conductors of heat and electricity
soft metals (lithium hardest
potassium softest)
low densities
shiny surfaces when freshly cut
low melting points
Why are Group I metals stored under oil?
So they do not touch air or water
Group I metals and oxygen
Burn in oxygen or air with characteristic flame colours to form white solid metal oxides
Group I metal oxides and water
React with water to form alkaline solutions of the metal hydroxide
Group I metals and water
React vigorously to form an alkaline solution of the metal hydroxide and hydrogen gas
Order of reactivity with water for lithium
sodium and potassium
Group I metals and halogens
React vigorously with halogens such as chlorine to form white metal halide salts
Trend down Group I
Reactivity increases down Group I
density increases up Group I
francium is predicted to be the most reactive Group I metal
Homework prediction: how does caesium compare to sodium?
Caesium is more dense than sodium
it will also be softer and more reactive
it will have a lower boiling point and melting point than sodium
Which elements are in Group II?
Beryllium
General physical properties of Group II metals
Harder than Group I metals
silvery-grey when pure and clean
tarnish quickly in air
good conductors of heat and electricity
Group II metals and oxygen
Burn in oxygen or air with characteristic flame colours to form solid white metal oxides
Group II metals and water
React with water
Trend down Group II
Reactivity increases down Group II
Which elements are in Group VII
the halogens?
Appearance of chlorine
bromine and iodine at room temperature
bromine is a red-brown liquid
iodine is a grey-black solid
Physical form of halogen elements
They exist as diatomic molecules
Trend in halogen state and melting/boiling point down the group
A gradual change from gas (chlorine)
melting and boiling point increase down the group
Halogens and hydrogen
React with hydrogen to produce hydrogen halides
Halogens and metals
React with metals to form ionic metal halides
Order of reactivity of chlorine
bromine and iodine with iron
Trend in halogen reactivity towards iron down the group
Elements in Group VII become more reactive with iron as you move up the group
Why does iodine have a higher boiling point than chlorine?
Iodine is a solid at room temperature so it requires more energy to break the forces between its molecules than bromine
chlorine is a gas so its intermolecular forces are far weaker
giving it the lowest boiling point of the three
Use of fluorine
Used
Use of chlorine
Used to make PVC plastic and household bleaches
Use of bromine
Used to make disinfectants
Use of iodine
Used in medicines and disinfectants
Which elements are in Group VIII
Group 0?
General properties of the noble gases
Colourless gases
monatomic
existing as single atoms rather than molecules
very unreactive
or chemically inert
Why are noble gases so unreactive?
Their atoms have stable electron configurations that are very difficult to change
Electron configuration of helium
2
Electron configuration of neon
2
Electron configuration of argon
2
Use of argon
Used in filament lamps
Use of neon
Used in advertising signs and in some types of lasers
Examples of transition elements
Copper
Where are transition elements found in the Periodic Table?
In the central block
General properties of transition elements
Less reactive than Groups I and II metals
harder and stronger
much higher densities
usually high melting points
the main exception being mercury
good conductors of heat and electricity
Coloured compounds of transition metals
Copper sulphate is turquoise blue
iron oxide is orange
chromium chloride is green
cobalt chloride is purple
Transition metals as catalysts
Many transition metals and their compounds are useful catalysts
Why don't transition metals corrode quickly?
They react more slowly with oxygen and/or water than many other metals
Diatomic elements that exist as molecules when uncombined
Nitrogen (N2)
What would you observe as calcium reacts with water?
Calcium reacts vigorously with cold water
the boiling tube becomes very hot
showing the reaction is exothermic
bubbles of hydrogen gas are given off and a white precipitate forms
together with an alkaline milky solution of calcium hydroxide
Word equation for calcium and water
Calcium + water → calcium hydroxide + hydrogen
How would magnesium's reaction with water differ from calcium's?
Magnesium will not be as reactive in water as calcium
in reality magnesium reacts very slightly
with a few bubbles of hydrogen forming on the surface before the reaction stops quickly
Three differences between Newlands' periodic table and the modern periodic table
Modern table is arranged by atomic number
the modern table has metals on the left and non-metals on the right
but Newlands placed the non-metals F and Cl in Group I
Newlands' table was missing many elements and had no noble gases
Why was Newlands' table different from the modern one?
Newlands arranged elements in order of relative atomic mass
What is wrong with Mendeleev's arrangement of tellurium and iodine by atomic mass?
Iodine's relative atomic mass is less than tellurium's
Why is this not a problem in the modern periodic table?
Iodine has a higher atomic number than tellurium
Predicted properties of rubidium compared to potassium
Lower melting and boiling point than potassium
more reactive than potassium