The equilibrium constant Kp and controlling the position of equilibrium

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11 Terms

1
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What is the mole fraction?

The number of moles of the specific gas / total number of moles in gas mixture

2
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What is partial pressure?

The mole fraction of a specific gas x the total pressure

3
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What does the sum of all the partial pressure equal?

The total pressure

4
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What will the total of the mole fractions always be?

1

5
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What is the equation for Kp?

knowt flashcard image
6
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What does Kp only include?

Gases - only gases have partial pressures

Other species must be ignored

7
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What happens to K at a set temperature?

K is constant and doesn’t change despite any modifications to concentration, pressure of presence of a catalyst

8
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What does cause K to change?

If the temperature is changed

9
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If the forward reaction if exothermic, what happens if the temperature is increases?

Equilibrium constant decreases

Raising the temperature decreases the equilibrium yield of products - equilibrium shifts to the left

numerator of Kp expression increases more

denominator of Kp increases to restore Kp

10
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If the forward reaction is endothermic, what happens if the temperature is increased?

Equilibrium constant increases

Increases equilibrium yield of products

11
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Does Kp change with pressure?

NO

only temperature