Final Exam Ch11/Ch12 Practice Problems

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Last updated 4:40 PM on 10/1/25
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The pKa of acetic acid is 4.74. The pKa for trifluoroacetic acid is 0.23. Explain why trifluoroacetic acid is a stronger acid than acetic acid.

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The boiling point of acetic acid and ethanol is 117.9 °C and 78.3 °C, respectively. Explain the substantially higher boiling point of acetic acid compared to ethanol.

Acetic acid forms a dimer with two molecules that have hydrogen bond IMFs. The increase in IMF strength increases the boiling point.

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<p>Name the following compound</p>

Name the following compound

N-methyldiethylamine

<p>N-methyldiethylamine</p>
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<p>Name the following compound</p>

Name the following compound

N-methylpropylamine

<p>N-methylpropylamine</p>
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<p>Fill in the products for the following multi-step reaction. The first reaction is nitration of benzene, followed by a reduction reaction.</p>

Fill in the products for the following multi-step reaction. The first reaction is nitration of benzene, followed by a reduction reaction.

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<p>Identify the set of reagents needed to complete the following reduction reaction.</p>

Identify the set of reagents needed to complete the following reduction reaction.

1.) LiAlH4, ether 2.) H3O+

(needs strong reductant)

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<p>Identify the set of reagents need to oxidize toluene to benzoic acid.</p>

Identify the set of reagents need to oxidize toluene to benzoic acid.

KMnO4, H2O

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In general, which carboxylic acid derivative has the fastest rate for nucleophilic acyl substitution reactions?

Acid halide

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<p>Identify the starting material needed to form the following acid chloride using thionyl chloride.</p>

Identify the starting material needed to form the following acid chloride using thionyl chloride.

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<p>What major organic product is formed in the following reaction?</p>

What major organic product is formed in the following reaction?

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<p>What major organic product is formed in the nucleophilic acyl substitution reaction shown?</p>

What major organic product is formed in the nucleophilic acyl substitution reaction shown?

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How are reactions between aldehydes/ketones and nucleophiles fundamentally different than reactions between acyl chlorides and nucleophiles?

Acyl chlorides have a leaving group, Cl- , whereas aldehydes/ketones do not.

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<p>Which of the following are primary amines?</p>

Which of the following are primary amines?

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<p>What is the major product of the following reaction?</p>

What is the major product of the following reaction?

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