a polymer is broken down into monomers which increases entropy
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anabolic/endergonic
monomers form a polymer which decreases entropy
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entropy
disorder and randomness
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enzyme
speeds up reactions and reduces the energy required to carry out reaction without being consumed by the reaction
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factors that affect enzymes
pH, heat, cold, competitive inhibitors, and non-competitive inhibitors
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cofactors (inorganic ions) and coenzymes (vitamins)
bind near or at active site to provide appropriate shape or substrate to bind
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competitive inhibitor
binds to active site to block substrates with binding
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non-competitive inhibitor
binds to allosteric site which alters the shape of the active site, preventing binding of substrate
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activator
binds to allosteric site to make the active site the appropriate shape to bind with substrate
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cooperativity
substrate itself is the activator for enzyme with quaternary structure
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purpose of cellular respiration
create a usable form of energy for the cell
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reactants in cellular respiration
glucose and oxygen
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products of cellular respiration
water and carbon dioxide
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what happens in glycolysis?
1 glucose molecule is broken down into 2 pyruvate molecules
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other than pyruvate, what are the products in glycolysis?
2 ATP and 2 NADH
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what is oxidized in glycolysis?
glucose
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what is reduced in glycolysis?
NAD+
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what is evidence glycolysis was earliest pathway to evolve?
does not require oxygen; Earth’s environment barely had oxygen long ago
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what happens in the immediate step in cellular respiration?
the 2 pyruvate (3-carbon) lose a carbon each to produce 2 acetyl-CoA (2-carbon)
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when pyruvate is turned into acetyl-CoA, what are the other products created?
2 CO2 and 2 NADH
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what happens in the Kreb’s cycle (citric acid cycle)?
acetyl-CoA and oxaloacetate form citric acid which then help generate electron carriers, NADH and FADH2 that bring electrons to the ETC
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what is released through the Kreb’s cycle?
6 NADH, 2 FADH2, 2 GTP (ATP), and 4 CO2
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proton-motive force
H+ concentration gradient; moves from high to low concentration
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how is the proton-motive force created in oxidative phosphorylation?
NADH and FADH2 release their electrons into the ETC which helps pump H+ ions from low to high contentration using active transport which builds up H+ ions in the inner membrance space
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how is ATP synthesized in oxidative phosphorylation?
H+ moves down concentration gradient through ATP synthase which provides energy for the formation of ATP from ADP and Pi
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what is the purpose of photosynthesis?
to produce sugar for cellular respiration
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reactants of photosynthesis
carbon dioxide and water
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products of photosynthesis
sugar and oxygen
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where do light-dependent reactions occur?
thykaloid membrane
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what happens in the photosystems?
electrons of the chlorophyll are energized and enter the ETC
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which photosystem does sunlight enter first?
photosystem II; once electrons are energized, it allows for the breakdown of water into oxygen and H+
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purpose of the first ETC in photosynthesis
pumps H+ from the stroma into the thykaloid space in order to create a proton-motive force which is used in ATP synthesis
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why do electrons enter another photosystem in photosynthesis?
electrons enter a second photosystem (photosystem I) to get re-energized by the sunlight and then enter the second ETC
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purpose of the second ETC in photosynthesis
provide energy to form NADPH from NADP+ and H+
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how do pigments in photosystem II re-generate electrons?
when water is broken down into oxygen and H+, electrons get replaced
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why do light-dependent reactions switch to cyclic electron flow periodically?
because ATP is depleted quickly in the next phase (Calvin cycle), a cyclie electron flow quickens the ATP generating process
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purpose of the Calvin cycle
use ATP and NADPH to convert CO2 to sugar
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where does the Calvin cycle take place?
stroma of a chloroplast
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first step of the calvin cycle: carbon fixation
enzyme, rubisco brings together 3 CO2 and 3 RuBP (5-carbon) to form unstable 3 6-carbon compounds which immediately breaks down into 6 3-carbon sugars
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second step in the Calvin cycle: reduction
6 ATP phosphorolate (add phosphorus) 6 3-carbon sugars; 6 NADPH then reduce the 6 sugars to create 6 G3P; one G3P is released leaving 5 in the cycle
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third and final step in Calvin cycle: regeneration
3 ATP are used to rearrage 5 G3P into 3 RuBP to restart the Calvin cycle again
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primary productivity
measures how much solar energy is converted to organic compounds in a period of time
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gross primary productivity (GPP)
total amount of oxygen or biomass produced
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net primary productivity (NPP)
amount of oxygen or biomass left over after producers perform cellular respiration