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Definitions and key terms
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aluminium oxide
Al2O3
2Na(s) + 2H2O(l) →
2NaOH(aq)+H2(g) (fizzing)
Sodium + cold water →
sodium hydroxide +hydrogen gas
magnesium +cold water →
magnesium hydroxide + hydrogen gas
Mg(s)+ H2O(g)→
MgO(s)+ H2(g)
magnesium +oxygen → magnesium oxide
white flame and white solid smoke
sodium +oxygen → sodium oxide
yellow flame and white solid
Aluminium + oxygen → aluminium oxide
white flame and white solid smoke
Silicon + oxygen → silicon oxide
white flame and white solid smoke
Phosphorus + oxygen → phosphorous oxide
white flame and white solid smoke
Sulfur + oxygen → sulfur dioxide
blue flame and acidic choking gas
VO2+
+5, yellow
VO2+
+4, blue
V3+
+2, green
V2+
violet
addition of zinc to vanadium
will reduce through successive oxidation state, going from yellow to violet
Lewis acid
electron pair donator
Lewis base
electron pair donator
metal ions with water
hydrated with H2O ligands around central metal ions
weaker ions in solution
2+ ions, (Fe2+, Cu2+ ) as they dissociate
stronger ions in solution
3+ ions, (Fe3+, Al3+),
metal ions in solution
acidic
why are 3+ ions in solution stronger acids than 2+ ions?
they dissociate more and have a greater attractive power to OH- (basic ions)
metal ions in solution + NaOH →
salt + water
neutralisation reaction
metal ions in solution act as acid
[Fe(H2O)6]2+ + 2OH- →
[Fe(H2O)4(OH)2] + 2H2O
green precipitate formed
[Cu(H2O)6]2+ +2OH- →
[Cu(H2O)4(OH)2] + 2H2O
blue precipitate
[Fe(H2O)6]3+ + 3OH- →
[Fe(H2O)3(OH)3] + 3H2O
purple precipitate
[Al(H2O)6]3+ + 3OH- →
[Al(H2O)3(OH)3] +3H2O
white precipitate