Gas Laws and Kinetic Molecular Theory

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100 Terms

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Gas Variables

Four variables: volume, pressure, temperature, moles.

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Kinetic Molecular Theory

Describes gas behavior based on particle motion.

<p>Describes gas behavior based on particle motion.</p>
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Volume

Space occupied by gas, measured in mL or L.

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Pressure

Force exerted by gas per unit area.

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Temperature

Measures kinetic energy of gas particles.

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Number of Moles

Amount of substance in a gas sample.

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Standard Temperature and Pressure (STP)

Conditions: 1 atm and 273 K (0°C).

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Elastic Collisions

No energy loss during gas molecule collisions.

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Attractive Forces

Negligible between gas molecules in motion.

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Gas Particle Motion

Particles in constant, random motion.

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Air Pressure

Pressure exerted by air surrounding us.

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Pressure Units

Measured in atm, mmHg, kPa, or torr.

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Pressure and Volume Relationship

Inversely related at constant temperature.

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Boyle's Law

P1V1 = P2V2; pressure-volume relationship.

<p>P1V1 = P2V2; pressure-volume relationship.</p>
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Temperature Effect on Pressure

Higher temperature increases gas pressure.

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Temperature Conversion

Celsius to Kelvin: °C + 273 = K.

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Gas Particle Collisions

Collisions with container walls create pressure.

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Effect of Adding Gas Particles

Increases pressure due to more collisions.

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Effect of Reducing Gas Particles

Decreases pressure due to fewer collisions.

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Effect of Increasing Temperature

Increases pressure with constant volume.

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Effect of Decreasing Temperature

Decreases pressure with constant volume.

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Effect of Container Size

Smaller container increases pressure.

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Boyle's Law Calculations

Used to find new pressure or volume.

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Gas Expansion

Volume increase leads to pressure decrease.

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Gas Compression

Volume decrease leads to pressure increase.

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Temperature and Kinetic Energy

Higher temperature means faster particle movement.

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Air Pressure Variation

Varies with altitude; higher at sea level.

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Gas Behavior Prediction

Use gas laws to predict changes.

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Pressure

Force exerted by gas particles per unit area.

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Volume

Space occupied by a gas.

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Temperature

Measure of average kinetic energy of particles.

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Direct Relationship

Both variables increase or decrease together.

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Inverse Relationship

One variable increases while the other decreases.

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Charles's Law

Volume directly varies with temperature at constant pressure.

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Gay-Lussac's Law

Pressure directly varies with temperature at constant volume.

<p>Pressure directly varies with temperature at constant volume.</p>
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Ideal Gas Law

PV=nRT; relates pressure, volume, temperature, and moles.

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Particles

Small units that compose gases, in constant motion.

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Elastic Collisions

Collisions where total kinetic energy is conserved.

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Capped Syringe

Demonstrates pressure-volume relationship in gases.

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Kelvin Temperature

Absolute temperature scale used in gas laws.

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Shock Wave

Pressure wave caused by explosive gas expansion.

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Pressure Units

Commonly measured in mmHg or atm.

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Constant Variables

Conditions that remain unchanged during an experiment.

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Volume Doubling Effect

Pressure halves when volume doubles at constant particles.

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Volume Halving Effect

Pressure doubles when volume is halved at constant particles.

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Temperature Doubling Effect

Pressure doubles when temperature is doubled at constant volume.

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Temperature Halving Effect

Pressure halves when temperature is halved at constant volume.

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Gas Behavior

Describes how gases respond to changes in conditions.

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Balloon Analogy

Illustrates gas expansion with temperature increase.

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Aerosol Can Pressure

Pressure increases when temperature rises in a closed container.

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Tire Pressure Change

Pressure increases with temperature during driving.

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Gas Expansion

Increase in volume due to temperature rise.

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Gas Compression

Decrease in volume due to pressure increase.

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Fixed Mass of Gas

Amount of gas that remains constant in calculations.

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Gas Laws Calculations

Mathematical applications of gas laws to find unknowns.

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Pressure-Volume Relationship

Describes how pressure changes with volume adjustments.

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Temperature-Pressure Relationship

Describes how pressure changes with temperature adjustments.

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Combined Gas Law

Relates pressure, volume, and temperature of gas.

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Boyle's Law

Pressure and volume of gas are inversely related.

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Charles's Law

Volume and temperature of gas are directly related.

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Gay-Lussac's Law

Pressure and temperature of gas are directly related.

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Dalton's Law of Partial Pressure

Total pressure equals sum of partial pressures.

<p>Total pressure equals sum of partial pressures.</p>
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Effusion

Gas escaping through a tiny hole.

<p>Gas escaping through a tiny hole.</p>
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Diffusion

Molecules move from high to low concentration.

<p>Molecules move from high to low concentration.</p>
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Avogadro's Hypothesis

Equal volumes of gas have equal particles.

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Gas Volume Calculation

Volume changes with temperature and pressure.

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Pressure Units

Commonly measured in atm, kPa, mmHg.

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STP

Standard Temperature and Pressure conditions.

<p>Standard Temperature and Pressure conditions.</p>
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Gas Law Equation

P1V1/T1 = P2V2/T2 for gas calculations.

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Initial Conditions

Starting pressure, volume, and temperature of gas.

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Final Conditions

Ending pressure, volume, and temperature of gas.

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Temperature Conversion

Convert Celsius to Kelvin by adding 273.15.

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Gas Behavior

Gases expand to fill their containers.

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Pressure Increase Effect

Higher pressure decreases gas volume.

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Volume Decrease Effect

Lower volume increases gas pressure.

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Gas Mixture

Combination of different gases in a container.

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Total Pressure Calculation

Sum of individual gas pressures in mixture.

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Gas Law Quiz

Assessment of understanding gas law principles.

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Temperature Increase Effect

Higher temperature increases gas volume.

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Volume Expansion

Gas expands when heated at constant pressure.

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Pressure Decrease Effect

Lower pressure increases gas volume.

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Gas Law Applications

Used in real-world scenarios like weather.

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Gas Collection

Collecting gas samples under specific conditions.

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Gas Constant

R = 0.0821 L·atm/(K·mol) for ideal gas.

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Gas Density

Mass per unit volume of gas.

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Graham's Law

Rate of diffusion inversely proportional to molar mass.

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Velocity of gas molecules

Inversely related to their mass.

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Diffusion

Process of molecules moving to lower concentration.

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Molar mass

Mass of one mole of a substance.

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Partial pressure

Pressure exerted by a single gas in a mixture.

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Ideal Gas

Hypothetical gas conforming to kinetic theory assumptions.

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Ideal Gas Law

PV = nRT; relates pressure, volume, temperature.

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Pressure (P)

Force exerted by gas per unit area.

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Volume (V)

Space occupied by gas, measured in liters.

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Number of moles (n)

Amount of substance measured in moles.

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Ideal gas constant (R)

Value varies based on pressure units used.

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Temperature (T)

Measured in Kelvin for gas law calculations.

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Kinetic molecular theory

Explains gas behavior based on particle motion.

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Rate of diffusion

Speed at which gas molecules spread out.

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Rate of effusion

Speed at which gas escapes through a hole.