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C to C single bond length
1.54Å
C to C single bond energy
355 kJ/mol
C to C double bond length
1.34Å
C to C double bond energy
730 kJ/mol
What are the 4 “weak” interactions?
Ionic interactions
Hydrogen bonds
VDW
Hydrophobic effect
What are the 2 things that make up the DNA backbone?
Alternating sugar & phosphate grps
Nitrogenous bases
How many bonds can A & T make?
2
How many bonds can C & G make?
3
Why does ssDNA for dsDNA in solution?
Aqueous environment overcomes ionic repulsion
H bonds ensure base pairing specificity
VDW & hydrophobic effect encourage base stacking
Do H bonds play a role in energetics of dsDNA formation?
No; play a role in base pairing specificity