Quantum eqs

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28 Terms

1
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λ_max T = 2.898 × 10⁻³ m·K

Wien's Displacement Law: Relates the temperature of a blackbody to the wavelength at which its emission is maximum. λ_max is the peak wavelength; T is the absolute temperature in kelvin.

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I = σT⁴

Stefan-Boltzmann Law: Gives the total power radiated per unit area by a blackbody. I is intensity (power per area); σ is the Stefan-Boltzmann constant; T is absolute temperature.

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u(ν)dν = (8πhν³ / c³) · [dν / (e^{hν/kT} − 1)]

Planck's Law: Describes the spectral energy density of blackbody radiation. u(ν) is energy density per frequency; ν is frequency; h is Planck's constant; c is speed of light; k is Boltzmann's constant; T is temperature.

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E = hν

Photon Energy: Energy carried by a single photon. E is energy; h is Planck's constant; ν is frequency.

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eV = hν − W

Photoelectric Effect Equation: Relates the maximum kinetic energy of emitted electrons to photon energy. eV is electron kinetic energy; V is stopping potential; W is the work function of the metal.

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|ψ⟩ = a|↑⟩ + b|↓⟩

General Spin Superposition: Any spin-½ state can be written as a linear combination of spin-up and spin-down states along the z-axis. a and b are complex probability amplitudes.

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|↑ₓ⟩ = (1/√2)|↑⟩ + (1/√2)|↓⟩

Spin Eigenstate Along x-Axis (Up): State giving +ℏ/2 when Sₓ is measured. Written in the z-basis.

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|↓ₓ⟩ = (1/√2)|↑⟩ − (1/√2)|↓⟩

Spin Eigenstate Along x-Axis (Down): State giving −ℏ/2 when Sₓ is measured.

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|↑ᵧ⟩ = (1/√2)|↑⟩ + (i/√2)|↓⟩

Spin Eigenstate Along y-Axis (Up): Eigenstate of Sᵧ with eigenvalue +ℏ/2. Imaginary coefficient encodes phase.

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|↓ᵧ⟩ = (1/√2)|↑⟩ − (i/√2)|↓⟩

Spin Eigenstate Along y-Axis (Down): Eigenstate of Sᵧ with eigenvalue −ℏ/2.

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|↑ₙ⟩ = cos(θ/2)|↑⟩ + e^{iφ} sin(θ/2)|↓⟩

General Spin-Up State: Spin-up along an arbitrary direction n. θ is the polar angle from z; φ is the azimuthal angle in the x-y plane.

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|↓ₙ⟩ = sin(θ/2)|↑⟩ − e^{iφ} cos(θ/2)|↓⟩

General Spin-Down State: Spin-down along an arbitrary direction n.

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1/λ_mn = R∞(1/m² − 1/n²)

Rydberg Formula: Calculates the wavelength of light emitted when an electron transitions from level n to m in hydrogen. R∞ is the Rydberg constant.

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L = nℏ

Bohr Quantization Condition: Angular momentum of an electron in a hydrogen atom is quantized. n is a positive integer; ℏ is reduced Planck's constant.

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r_n = (4πϵ₀ / Ze²)(n²ℏ² / m)

Bohr Radius Formula: Radius of the nth orbit in a hydrogen-like atom. Z is atomic number; m is electron mass.

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λ = h/p

De Broglie Wavelength: Associates a wavelength with a particle of momentum p, demonstrating wave-particle duality.

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Ŝ_z|↑⟩ = +ℏ/2 |↑⟩

Spin Operator Eigenvalue Equation: Measuring S_z on a spin-up state yields +ℏ/2.

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Ŝ_z|↓⟩ = −ℏ/2 |↓⟩

Spin Operator Eigenvalue Equation: Measuring S_z on a spin-down state yields −ℏ/2.

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p̂ = −iℏ ∂/∂x

Momentum Operator: Quantum mechanical operator for momentum in the position representation.

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Ĥ = iℏ ∂/∂t

Hamiltonian Operator: Governs time evolution of a quantum state and corresponds to total energy.

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ΔA = √(⟨²⟩ − ⟨Â⟩²)

Definition of Uncertainty: Standard deviation of observable A, measuring spread of outcomes.

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ΔAΔB ≥ ½ |⟨[Â, B̂]⟩|

Generalized Uncertainty Principle: Non-commuting operators cannot be simultaneously known with arbitrary precision.

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E_n = n²π²ℏ² / (2mL²)

Particle in a Box Energy Levels: Allowed energies for a particle confined to an infinite square well of width L.

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N = N₀ e^{−λt}

Radioactive Decay Law: Describes exponential decay of unstable nuclei. λ is the decay constant; t is time.

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Locality

the principle of locality states that an object is influenced directly only by its immediate surroundings.

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Realism

The stance that properties have definite values independent of measurement is realism.

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completeness

any physical state can be fully described as a superposition (linear combination) of basis states (like energy or position eigenstates)

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Copenhagen interpretation

states a quantum particle exists in a superposition of all its possible states until a measurement is made