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expanded octet
where a central atom in a molecule holds more than eight valence electrons, violating the standard octet rule
when dose the expanded octet rule occur
it occurs with elements in period 3 and below
why can elements after period 3 use the expended octet rule
By utilizing their d orbital
resonances
are different ways to represent the same molecule by redistributing electrons among bonds
formal charge
calculated charge assigned to an individual atom within a molecule or ion to determine the most plausible Lewis structure
how is formal charge used to predict when a centrel atom will have an incomplete or expanded octet
helps identify the most stable Lewis structure by minimizing charge separation ( is ideal). If using the octet rule results in large formal charges (e.g., or ) on a central atom, it suggests an expanded octet (more bonds) is necessary to bring the charge closer to , or an incomplete octet (fewer bonds) is acceptable
how is formal charge used to predict the correct structure from several Lewis dot structers that the octet rule deems valid
by calculating the hypothetical charge distribution among atoms, allowing chemists to select the most stable and realistic structure.
when dose a covalent compound have a resonances structure?
more than one valid picture (Lewis structure) for the same molecule
non meticallic and metalloids are
covelent bonds
Ionic compounds (metal + nonmetal) don't use prefixes because
their ratios are fixed by charge balancing,
Covalent compounds (nonmetal + nonmetal) use prefixes (di-, tri-, tetra-) because
, e.g., . Covalent compounds (nonmetal + nonmetal) use prefixes (di-, tri-, tetra-) because they can combine in multiple ratios, e.g., vs. . Ionic uses roman numerals to specify metal charge.
transisition metals are located from
groups 3 to 12 on the periodic table.
Roman numerals are used in naming ionic compounds containing
metals that can have multiple charges (usually transisition metals)
Without a numeral, "iron chloride" could mean two different substances
The numeral clarifies exactly which metal ion is present.
roman numerals represent the charge not the
amount of valence e-s
what is Electronegativity
Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons.
electronegativty increases from where to where in the periodic table
increases from bottom left to top right
other elements included as transition mentals when naming chemical formulas
lead, tin, iron (Fe), copper (Cu), zinc (Zn), titanium (Ti), nickel (Ni), cobalt (Co), tungsten (W), gold (Au), silver (Ag), platinum (Pt), and manganese (Mn
tetra
4
penta
5
hexa
6
hepta
7
octa
8
nona
9
deca
10
equation to figure out how many lone pairs there are
LP= Ve-8(n= number of atoms)/ 2
LP stands for
one pair of e-s