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chiral center
atom with 4 different groups attatched
do chiral centers rotate plane polarized light
yes
when do chiral centers not rotate plane polarized light
with racemic mixtures or meso compounds
absoulte configuration
assigning priority to substituents off of chiral center (r vs s)
racemic mixture
50% of each absolute configuration
meso compound
plane of symmetry between chiral centers
stereochemistry of fischer projections
horizontal = wedge
vertical = dash