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ideal gas equation
PV=nRT
sulfur dioxide + sodium hydroxide
SO2 + 2NaOH → Na2SO3 + H2O
sodium sulpite + sulfur dioxide
Na2SO3 + H2O + SO2 → 2NaHSO3
reaction which occurs when removing sulphur dioxide from flue gases in power stations
CaO + SO2 → CaSO3
sodium oxide + chloric (VII) acid
NaOH + HClO4 → NaClO4 + H2O
chlorine oxide + water (reversible reaction)
Cl2O + H2O → HOCl
units for PV=nRT
pressure = pascals, volume = m³, temperature = kelvin
kelvin to celsius
k = c + 273
percentage atom economy
mr of desired product/mr of all reactants x 100
equation relation kinetic energy, mass, velocity
KE =1/2(mv²)
units for KE = 1/2(mv²)
KE = joules, m = kg, v = m/s
calorimetry equation
Q=mc(delta T)
Gibbs Free Energy equation
delta G = delta H - T(delta S)
units for gibbs free energy
delta G = kJ/mol, delta H = kJ/mol, T = kelvin, delta S = J/(Kelvin x mol)
partial pressure for kP equation
mol fraction x total pressure
magnesium oxide + water
MgO(s) + H2O(l) → Mg(OH)2(aq)
aluminium oxide + water
no reaction
phosphorus oxide + water
P4O10(s) + 6H2O(l) → 4H3PO4(aq)
sulfur dioxide + water
SO2(g) + H2O(l) → H2SO3(aq)
sulfur trioxide + water
SO3(g) + H2O(l) → H2SO4(aq)
iron^(2+) and manganate
5Fe^2+ + MnO4^- + 8H^+ → 5Fe^3+ + Mn^2+ + 4H2O
ethanedioate and manganate
2MnO4^- + 16H^+ + 5C2O4^(2-) → 2Mn^(2+) + 8H2O + 10CO2
colour of Fe2+
green
colour of MnO4-
intense purple
colour of Fe3+
pale violet
colour of Mn2+
pale pink
overall equation for hydrogen oxygen fuel cell
O2(g) + 2H2(g) → 2H2O
the reaction which occurs at the negative electrode of an alkaline hydrogen oxygen fuel cell?
2OH-(aq) + H2(g) → 2H2O(l) + 2e-
what reaction occurs in an alkaline hydrogen-oxygen fuel cell at the positive electrode?
1/2O2(g) + H2O(l) +2e- → 2OH-(aq)
what reaction occurs in an acidic hydrogen-oxygen fuel cell at the negative electrode?
H2(g) → 2H^+(aq) + 2e^-
what reaction occurs in an acidic hydrogen-oxygen fuel cell at the positive electrode?
O2(g) + 4H+(aq) + 4e^- → 2H2O(l)
what reaction occurs in at the positive electrode of a lithium cell?
Li^+ + CoO2 + e^- → Li^+[CoO2]^-
what reaction occurs in at the negative electrode of a lithium cell?
Li → Li+ + e^-
reduction of titanium (IV) chloride using magnesium
TiCl4 + 2Mg → Ti + 2MgCl2
sodium thiosulfate + HCl
Na2S2O3(aq) + 2HCl(aq) → 2NaCl(aq) + S(s) +SO2(g) + H2O(l)
overall reaction between iodide an persulfate ions
S2O8^(2-) + 2I^- → SO4^(2-) + I2
equation for pH using [H+]
pH = -log[H+]
equation for Kw
Kw= [OH^-] [H^+]
equation for pKa using Ka
pKa = - logKa
equation for sodium chloride + sulfuric acid
H2SO4 + NaCl → NaHSO4 + HCl
2 reactions for sodium bromide + H2SO4
NaBr + H2SO4 → NaHSO4 + HBr. 2HBr + H2SO4 → SO2 + Br2 + 2H2O.
2 reactions for sodium iodide + H2SO4
NaI + H2SO4 → NaHSO4 + HI. 8HI + H2SO4 → H2S + 4H2O + 4I2
metal oxide + water →
metal hydroxide
metal hydroxide + acid →
salt + water
metal carbonate + acid →
salt + water + carbon dioxide
sodium + oxygen reaction
4Na + O2 → 2Na2O(s)
magnesium + oxygen reaction
2Mg + O2 → 2MgO(s)
aluminium + oxygen reaction
4Al + 3O2 → 2Al2O3(s)
silicon + oxygen reaction
Si + O2 → SiO2(s)
phosphorus + oxygen reaction
4P + 5O2 → P4O10(s)
sulfur + oxygen reaction (no catalyst)
S + O2 → SO2
sulfur + oxygen reaction with catalyst
2S + 3O2 → 2SO3
sodium oxide + water reaction
Na2O + H2O → 2NaOH
pH of solution formed from sodium oxide in water
14
reaction for aluminium oxide + water
no reaction
reaction for silicon oxide + water
no reaction
pH of solution formed from phosphorus oxide in water
2
reaction for sulfur dioxide + water
SO2 + H2O → H2SO3
pH of solution formed from sulfur dioxide in water
2-3
reaction for sulfur trioxide + water
SO3 + H2O → H2SO4
pH of solution formed from sulfur trioxide in water
0-1
aluminium oxide + hydrochloric acid reaction
Al2O3+ 6HCl → 2AlCl3 + 3H2O
aluminium oxide + sodium hydroxide reaction
Al2O3 + 2NaOH + 3H2O → 2NaAl(OH)4
phosphorus oxide + sodium hydroxide reaction
P4O10 + 12NaOH → 4Na3PO4 + 6H2O
sodium oxide + hydrochloric acid reaction
Na2O + 2HCl → 2NaCl + H2O
magnesium oxide + hydrochloric acid reaction
MgO + 2HCl → MgCl2 + H2O
silicon dioxide + sodium hydroxide reaction
SiO2 + 2NaOH → Na2SiO3 + H2O
what reaction occurs in the blast furnace extraction of iron
SiO2 + CaO → CaSiO3
sodium hydroxide + chloric acid
NaOH + HClO → NaClO + H2O
vanadium (V) oxide ion + zinc
2VO2^+ + 4H^+ + Zn → 2VO^(2+) + 2H2O + Zn^(2+)
vanadium (IV) oxide ion + zinc
2VO^(2+) + 4H^+ + Zn → 2V^(3+) + Zn^(2+) + H2O
vanadium (III) ion + zinc
2V^(2+) + Zn → 2V^(2+) + Zn^(2+)
overall reaction for the contact process
SO2 + 1/2O2 → SO3
2 reactions for vanadium (V) catalyst in the contact process
SO2 + V2O5 → SO3 + V2O4. 1/2O2 + V2O4 → V2O5.
overall ionic equation for peroxodisulfate ions + iodide ions
S2O8^(2-) + 2I^- → I2 + 2SO4^(2-)
2 reactions for Fe^(2+) as a catalyst for peroxodisulfate ions and iodide ions
S2O8^(2-) + 2Fe^(2+) → 2Fe^(3+) + 2SO4^(2-). 2Fe^(3+) + 2I^- → I2 + 2Fe^(2+)
manganate ions + ethanedioate ions overall equation
2MnO4^- + 8H^+ + 5C2O4^(2-) → 2Mn^(2+) + 4H2O + 10CO2
2 reactions showing autocatalysis of reaction between managanate ions and ethanedioate ions
2MnO4^- + 8H^+ + 4Mn^(2+) → 5Mn^(3+) + 4H2O. 2Mn^(3+) + C2O4^(2-) → 2CO2 + 2Mn^(2+)
overall reaction for ozone depletion
2O3 → 3O2
fermentation reaction
C6H12O6 → C2H5OH + 2CO2
Tollens reagent reaction for positive test
[Al(NH3)2]^+ + e^- → Ag(s) + 2NH3
generation of NO2^+ electrophile
HNO3 + 2H2SO4 → NO2^+ + 2HSO4^- + H3O^+
Rf value
distace travelled by substance/distance travelled by solvent