Organic Chemsitry - Aldehydes and Ketones i: electrophilicity and Oxidation Reduction

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MCAT Chapter 6

Last updated 3:18 PM on 6/19/26
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9 Terms

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Ketone

two alkyl groups bonded to the carbonyl

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Aldehyde

one alkyl group and one hydrogen bonded to a carbonyl

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Properties of boiling point

the dipole moment in polar carbonyl group increase intramolecular attractions, causing elevation in boiling point, but less than in alcohols due to lack of hydrogen bonding.

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Hydration reaction

water adds to carbonyl forming geminal diol

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Hemiacetal

one equivalent of alcohol reacts with aldehyde

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Hemiketal

one equivalent of alcohol reacts with a ketone

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Acetal

equivalent of alcohol reacts with hemiacetal

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Ketal

equivalent of alcohol reacts with hemiketal

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What do imines tautomerize to

enamines