Orgo Ch 10 adding to double bond Mechanisms

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Last updated 8:27 AM on 4/25/26
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4 Terms

1
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Radical HBr addition (alkenes & alkynes) Reagents:

HBr+ ROOR, hv (light), or heat (anti-markonikov)

<p>HBr+ ROOR, hv (light), or heat (anti-markonikov) </p>
2
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Carbene addition to alkenes Reagents

CHCl3 or CHBr3 + strong base ( KOTBU, NaOH) (cyclopentane formation)

<p>CHCl3 or CHBr3 + strong base ( KOTBU, NaOH) (cyclopentane formation) </p>
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Simmons - Smith Reagents:

CH2I2 + (Zn(Cu)) + ether solvent

<p>CH2I2 + (Zn(Cu)) + ether solvent</p>
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Polymerization of alkenes Reagents:

heat + peroxide (free- rad) or H2SO4 OR HF + BF3, H2O (cationic)