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In what form is most nitrogen (95–98%) found in wetland soils?
Organic compounds
What happens to denitrification when temperature increases?
It increases (microbial activity speeds up)
What happens to denitrification when oxygen decreases?
It increases (denitrification is anaerobic)
Which process removes nitrogen from the biosphere to the atmosphere?
denitrification
What nitrogen process needs oxygen?
Nitrification NH4+ → NO3-
What nitrogen process happens in anerobic conditions?
denitrification
what is mineralization?
Break down of organic nitrogen to ammonium (ammonification)
What is immobilization?
The buildup of organic matter where inorganic Nitrogen converts to organic matter
What are forms of organic matter
Proteins (amino acids), Amino sugars, urea, and nucleic acids
What is biological N2 fixation?
When bacteria convert atm nitrogen into a usable form
Which process converts nitrogen to a gas and releases it to the atmosphere?
Ammonia volatilization
Does mineralization remove nitrogen from the system?
No (it converts organic → inorganic nitrogen)
Does plant uptake remove nitrogen from the system?
No (it stores it in biomass)
if C:N > ~25
immobilization dominates, C:N < ~25 → Ammonification dominates
Under anaerobic conditions, what process is generally favored?
Slower decomposition but still follows C:N rule (high C:N → immobilization)
What happens to nitrogen during denitrification?
NO₃⁻ → N₂ (reduction, nitrogen gas released)
What happens to nitrogen during dissimilatory nitrate reduction (DNRA)?
NO₃⁻ → NH₄⁺
Which process involves the MOST electron transfer?
Denitrification (NO₃⁻ → N₂)
Which nitrogen process dominates under highly reduced (low oxygen) conditions?
DNRA (NO₃⁻ → NH₄⁺)
What does alkaline phosphatase indicate?
Phosphorus limitation (low available P)
How does phosphatase activity change when phosphorus is limited?
It increases
Where is phosphatase activity typically highest?
Plant litter layer
How does phosphatase activity change with soil depth?
Decreases with depth
What is the largest global nitrogen pool?
Atmosphere
Which is larger: soil nitrogen or living organisms?
soil
What is porewater P?
Dissolved phosphorus in sediment water
Name an inorganic mechanism that retains phosphorus in soils
sorption
Name an organic mechanism that retains phosphorus
microbial uptake
what is EPC?
The concentration where no net P sorption or release occurs
what does low EPC mean?
System absorbs P (less impacted)
What does high EPC mean?
system releases P
what lake would be more impacted high ECP or low?
High ECP
What is eutrophication?
Excess nutrients → algal blooms → oxygen depletion
Why is nitrogen pollution harmful to humans?
Contaminates drinking water (e.g., nitrate toxicity)
How does nitrogen affect food production?
increases crop yields
Why are phosphorus fertilizers important?
increase crop productivity
What is a major concern with phosphorus use?
the depletion of phosphate rock bc it is non-renewable
How can we sustain phosphorus for future agriculture?
Use fertilizers more efficiently
Recycle phosphorus (waste/manure)
Reduce runoff losses
Manage soils for better retention
What happens to nitrogen cycling if denitrification is removed?
Nitrogen accumulates in the system (less loss to atmosphere)
What happens to available nitrogen over time without denitrification?
it increases
What happens to primary productivity when available nitrogen increases?
it increases
What environmental issue can result from excess nitrogen?
Eutrophication (algal blooms, hypoxia)
What is the main cause of harmful algal blooms in Lake Pontchartrain?
Nutrient input from the Mississippi River
Why is denitrification important for ecosystems?
It removes excess nitrogen and prevents buildup
What happens if nitrogen is not removed efficiently?
Nutrient pollution and ecosystem imbalance
Why do tropical soils require more phosphorus fertilizer?
High sorption capacity locks up phosphorus
What happens to added phosphorus in tropical soils?
it binds to minerals and becomes unavailable
What happens if nitrogen is abundant but phosphorus is limited?
Growth is still limited (P becomes the limiting nutrient)
Why does NH₄⁺ diffuse slower than PO₄³⁻?
NH₄⁺ is positively charged and binds to negatively charged soil particles
Where is ammonium (NH₄⁺) typically highest?
In deeper, anaerobic soils
Why does ammonium increase with depth?
Less oxygen → more mineralization + less nitrification
What direction does ammonium flux usually go?
Upward toward the water column
Which nitrogen forms act as electron acceptors?
NO₃⁻ (nitrate) and NO₂⁻ (nitrite)
If denitrifiers are removed, what nitrogen process dominates?
Nitrogen fixation + retention processes
What happens to N₂ gas cycling without denitrification?
Less N returns to atmosphere → buildup in system
What’s the key difference between nitrogen and phosphorus limitation?
Nitrogen = often mobile and lost via gas
Phosphorus = often stored and limited by soil binding
What’s the link between nitrogen buildup and eutrophication?
More N → more algal growth → oxygen depletion
What does the Carbon/Nitrogen (C/N) ratio tell you about decomposition?
Microbes need C/N ≈ 10 to grow
High C/N (too much carbon): not enough nitrogen → microbes take N → immobilization
Low C/N (more nitrogen): extra N released → mineralization
Aerobic systems need more N