Allan we are so fucked Ver 0.3

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awe shiet

Last updated 5:49 AM on 6/2/26

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43 Terms

1

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<p>enamine</p>

enamine

<p></p>

2

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<p>mechanism</p>

mechanism

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3

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<p>saponification</p>

saponification

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4

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<p>mechanism</p>

mechanism

saponification

<p>saponification</p>

5

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term image

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6

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<p>mechanism</p>

mechanism

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7

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<p>reagents + mechanism</p>

reagents + mechanism

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8

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<p>beta-keto ester</p>

beta-keto ester

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9

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<p>beta-keto ester, mechanism</p>

beta-keto ester, mechanism

makes ketones

<p>makes ketones</p>

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<p>(malonic ester)</p>

(malonic ester)

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11

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<p>mechanism (malonic ester)</p>

mechanism (malonic ester)

malonic ester + saponification

<p>malonic ester + saponification</p>

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<p>mechanism</p>

mechanism

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14

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<p>Aldol</p>

Aldol

if you see only one aldehyde or ketone assume it’s 2 eq.

<p>if you see only one aldehyde or ketone assume it’s 2 eq.</p>

15

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<p>mechanism</p>

mechanism

if you see alkene next to carbonyl croup = aldol (practice retrosynthesis)

<p>if you see alkene next to carbonyl croup = aldol (practice retrosynthesis)</p>

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<p>Knoevenagel (EWGs)</p>

Knoevenagel (EWGs)

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<p>mechanism * Knoevenagel</p>

mechanism * Knoevenagel

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<p></p>

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<p>mechanism*</p>

mechanism*

aromaticity

<p>aromaticity</p>

20

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<p>Michael rxn</p>

Michael rxn

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<p>mechanism* Michael rxn</p>

mechanism* Michael rxn

1,4 addition.

thermodynamic product.

soft nucleophile

<p>1,4 addition. </p><p>thermodynamic product. </p><p>soft nucleophile</p>

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Hard nucleophile

<p>Hard nucleophile</p>

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<p>mechanism</p>

mechanism

hard nucleophile

<p>hard nucleophile</p>

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25

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<p>mechanism</p>

mechanism

1,4 addition

<p>1,4 addition</p>

26

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<p>Intra-molecular Aldol</p>

Intra-molecular Aldol

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<p>mechanism*</p>

mechanism*

ring size usually 5 or 6 but can be 4 occasionally

<p>ring size usually 5 or 6 but can be 4 occasionally</p>

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<p>crossed aldol</p>

crossed aldol

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<p>mechanism</p>

mechanism

if you see alkene next to carbonyl croup = aldol (practice retrosynthesis)

<p>if you see alkene next to carbonyl croup = aldol (practice retrosynthesis)</p>

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<p>mechanism</p>

mechanism

if you see alcohol next to carbonyl croup = could be aldol (practice retrosynthesis)

<p>if you see alcohol next to carbonyl croup = could be aldol (practice retrosynthesis)</p>

32

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<p></p>

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<p>mechanism*</p>

mechanism*

Pka ketone = 19, Pka = 24

(so ketone is nucleophile)

+ makes two ketones

<p>Pka ketone = 19, Pka = 24 </p><p>(so ketone is nucleophile) </p><p>+ makes two ketones</p>

34

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<p>Claisen condensation </p><p>(Ester + Ester)</p>

Claisen condensation

(Ester + Ester)

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<p>mechanism</p>

mechanism

Way to make beta-keto ester.

Claisen condensation (Ester + Ester)

<p>Way to make beta-keto ester. </p><p>Claisen condensation (Ester + Ester)</p>

36

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<p>Dieckmenn rxn</p>

Dieckmenn rxn

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<p>mechanism</p>

mechanism

Dieckmenn rxn

easy way to make 5 member rings

<p>Dieckmenn rxn</p><p>easy way to make 5 member rings</p>

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<p>Crossed Cleisen</p>

Crossed Cleisen

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<p>Mechanism </p><p>Crossed Cleisen</p>

Mechanism

Crossed Cleisen

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<p>Robinson annulation</p>

Robinson annulation

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<p>Mechanism*</p><p>Robinson annulation</p>

Mechanism*

Robinson annulation

1,4 addition + aldol

if you see alkene next to carbonyl croup = aldol (practice retrosynthesis)

<p>1,4 addition + aldol</p><p>if you see alkene next to carbonyl croup = aldol (practice retrosynthesis)</p>

42

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<p>Nazarov cyclization</p>

Nazarov cyclization

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<p>mechanism***</p><p>Nazarov </p>

mechanism***

Nazarov

stereochemistry!!!

<p>stereochemistry!!!</p>