Unit 4 Reagents (Alkenes + Alkynes)

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Last updated 11:55 PM on 5/5/26
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20 Terms

1
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Alkene Hydrogenation

H2 + Pd/C or Pt0

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Alkene Hydrohalogenation

HCl, HBr, HI

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Alkene Hydration Carbocation

H2SO4 + H2O

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Alkene Isomerization

H2SO4

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Alkene Halogenation

Cl2, Br2

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Alkene Halohydrin Synthesis

Br2, Cl2 and HOH

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Alkene Oxymercuration-Reduction

  1. Hg(OAc)2, HOH

  2. NaBH4, NaOH

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Alkene Hydroboration-Oxidation

  1. BH3

  2. H2O2, NaOH

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Alkene Epoxidation

mCPBA, peracetic acid, or trifluoroperacetic acid

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Alkene Syn-Dihydroxylation

  1. OsO4 (stoich)

    1. H2S or Zn metal

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Alkene Ozonolysis (Reductive Workup)

  1. O3

  2. S(CH3)2

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Alkene Ozonolysis (Oxidative Workup)

  1. O3

  2. H2O2, H2O

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Alkyne Reduction

H2 and Pd/C or Pt0

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Alkyne Partial Reduction Cis Alkene

H2 and Pd/CaCO3, Pb(OAc)2, and Quinoline

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Lindlar’s Catalyst

Pd/CaCO3, Pb(OAc)2, and Quinoline

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Alkyne Partial Reduction Trans Alkene

Na metal (radical), NH3 (l)

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Alkyne Hydrohalogenation

HCl, HBr

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Alkyne Halogenation

Br2, Cl2

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Alkyne Hydration + Carbonyl Most Subbed

HgSO4, H2SO4 and H2O

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Alkyne Hydration Hydroboration-Oxidation Carbonyl Least Subbed

  1. (C6H11)2BH

  2. H2O2, NaOH