Chem 31 Final - Alkene Addition Reactions

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Last updated 6:53 PM on 6/7/26
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12 Terms

1
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H-X

Markovnikov Hydrohalogenation - X goes on more substituted carbon of the alkene

<p>Markovnikov Hydrohalogenation - X goes on more substituted carbon of the alkene</p>
2
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H-X + ROOR

Anti-Markovnikov Hydrohalogenation - X goes on less substituted carbon of the alkene

<p>Anti-Markovnikov Hydrohalogenation - X goes on less substituted carbon of the alkene</p>
3
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H2O, H2SO4

Hydration - adds OH and H group

<p>Hydration - adds OH and H group</p>
4
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  1. Hg(OAc)2, H2O

  2. NaBH4

Oxymercuration-Demurcuration - adds OH with Hg intermediate

<p>Oxymercuration-Demurcuration - adds OH with Hg intermediate</p>
5
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  1. BH3*THF

  2. H2O2, NaOH

Hydroboration-Oxidation (syn speecific) adds H and OH group with BH2 intermediate

<p>Hydroboration-Oxidation (syn speecific) adds H and OH group with BH<sub>2</sub> intermediate</p>
6
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H2, Pd(catalyst)

Catalytic Hydrogenation - adds H2 in syn specific addition

<p>Catalytic Hydrogenation - adds H<sub>2</sub> in syn specific addition</p>
7
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X-X (Br2, Cl2)

Halogenation - adds 2 X in anti addition

<p>Halogenation - adds 2 X in anti addition</p>
8
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X-X, H2O

Halohydrin Formation

<p>Halohydrin Formation</p>
9
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mCPBA

Epoxidation

<p>Epoxidation</p>
10
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  1. mCPBA

  2. H3O+

Anti-Dihydroxylation - adds 2 OH groups in anti

<p>Anti-Dihydroxylation - adds 2 OH groups in anti</p>
11
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KMnO4 or OsO4

Syn-Dihydroxylation - adds 2 OH groups in syn

<p>Syn-Dihydroxylation - adds 2 OH groups in syn</p>
12
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O3, DMS

Ozonolysis - separates double bond and puts O on them — creates ketone and aldehyde group

<p>Ozonolysis - separates double bond and puts O on them — creates ketone and aldehyde group</p>