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Contact Herbicides
result in rapid injury/death to contacted tissue, but do not move through the plant
Systemic Herbicides
Absorbed by the plant and transported through the plant tissue to kill all parts of the plant, tend to work slower
Foliar Treatment
Sprayed directly on leaves of floating and emergent plants
Submersed Treatments
Applied as liquids or granules to the water column to achieve a target concentration
Copper herbicide
Fast acting CONTACT herbicide
Often used in potable water and irrigation systems
Lethal to some fish
Diquat Herbicide
Fast acting CONTACT herbicide
Absorbed and interferes with photosynthesis
Turbidity can inactivate it
Endothall
CONTACT herbicide
Used for large scale early season treatments
Available in amine salt for algae and plants or potassium salt for plants
Carfentrazone and Flumioxazin
CONTACT herbicide
PPO inhibitors causing cell membrane damage and necrosis
Carfentrazone: narrow spectrum, highly selective
Flumioxazin: broader spectrum
Highly sensitive to pH
2, 4-D
SYSTEMIC herbicide
Oldest herbicide in US
Auxin mimic causes plant to grow to death
Selective for Dicot
Florpyrauxifen-benzyl
SYSTEMIC herbicide
New auxin mimic that targets both monocots and dicots
Highly active at very low concentrations
Glyphosate and Imazapyr
SYSTEMIC herbicides
Only for foliar treatment
Glyphosate inhibits EPSPS enzyme and in inactivate by water and soil
Imazapyr inhibits ALS enzyme and is active in soil
Fluridone
SYSTEMIC herbicide
targets PDS enzyme and lets chlorophyll break down, causing bleaching
Very long contact time
Topramezone
SYSTEMIC herbicide
Inhibits HPPD enzyme, causes bleaching
Applied to actively growing plants, provides alternative for resistant plants
ALS (acetolactate synthase) inhibitors
Penoxsulam, Imazamox, Bispyribac-sodium
Used in combo with others to manage herbicide resistance
Activator Adjuvants
Surfactants, help herbicide break through waxy leaf cuticle
Utility Adjuvants
Reduce spray, foaming, or other handling issues
Adjuvants
Added to herbicide to modify activity or application
Impact of Thermocline on Herbicide use
When layers don’t mix, herbicides stay in upper layers and weeds in lower areas survive
Granular application are needed to overcome this
Diquat trade names
Tribune
Endothall Trade Name
Aquathol
Flumioxazin trade name
Flumigard
Glyphosate Trade Name
AquaNeat
Fluridone Trade Name
Sonar
Requirements for Herbicide Registrations
80-120 different studies over 6-10 years
Data must assess safety for human and non-target organism, as well as measure tolerance levels
What are pesticides regulated under?
FIFRA: Federal Insecticide Fungicide and Rodenticide Act
EPA: Environmental Protection Agency
Role of the EPA in herbicides
regulates them through pesticide labels
How is selectivity achieved in aquatic systems
herbicide choice, dosage, and timing to target one species among others
Concentration and Exposure Time (CET)
plants must be exposed to a lethal concentration over a specific time to be effective before the chemical dissapates
what do water conditioners do?
they bind to minerals in the water to prevent them from deactivating the herbicide
How does resistance affect treatment
plants that survive repeated exposure can cause a population to become resistant, so varying or combining the herbicide used, and maintaining a high efficacy can prevent this
How do Herbicides breakdown
some break down via photolysis, microbial action, or hydrolysis, while some bind to sediment to become inactive
Risk of Herbicides to fish
most are non-toxic since they target plant pathways, more concern for O2 depletion due to decay of vegetation, so treat in smaller areas
What is Integrated Plant Management
using multiple actions to achieve long term control, such as chemical, mechanical, and biological techniques