Quizbowl Chemical Compounds I

Oxidation of isopropanol

Acetone

Cooling bath when mixed w dry ice

Acetone

Jones oxidation = _ + chromic acid

Acetone

Natural by-product of fatty acid breakdown

Acetone

Carbonylated in Cativa process

Alcohols

used to precipitate DNA

Alcohols

Primary via reducing aldehydes

Alcohol

Secondary via reducing ketones

Alcohols

Dehydration produces ethers

Alcohols

Hydroboration-oxidation converts alkenes to __

Alcohols

Silyl ethers used to protect

Alcohols

Fischer esterification

Alcohols

Grignard reagent + carbonyl group =

Alcohols

Aqua regia used to dissolve gold/platinum

HCl

Clemmensen Reduction w/ Hg

HCl

“Fuming” above 16 M

HNO3

Synthesized in Ostwald Process

HNO3

Purified in Birkeland-Eyde process

HNO3

Millon’s Test

HNO3

Xanthoproteic reaction

HNO3

Synthesized in Haber Process

Ammonia

Used in Ostwald Process

Ammonia

Highest specific heat

Ammonia

Wohler used to synthesize urea

Ammonia

Solvates alkali metals’ electrons

Ammonia

double bonded hydrocarbon

Alkenes

cis and trans isomers

Alkenes

Diels-Alder reaction

Alkenes

Grubbs catalyst

Alkenes

Markovnikov

Alkenes

Keeling curve

CO2

Cause of ocean acidification

CO2

“Drying” reaction

CO2

Acidosis

CO2

Supercritical fluid used as decaffeinator

CO2

Passed thru limewater

CO2

Turns CoCl2 purple

H2O

Benzene used to entrain w/ ethanol

H2O

Sharpless studied rate accelerations for

H2O

Broken down in sulfur-iodine cycle

H2O

Bernal + Fowler made first 4-point model for

H2O

__ + hydroxyl = phenol

Benzene

__ + methyl = toluene

Benzene

Used in method of DNA extraction

Benzene

Kathleen Lonsdale confirmed structure

Benzene

Used as solvent in paint thinner

Benzene

Dinitro methyl form used as explosive

Benzene

Apatites

Phosphate

“Pyro” form

Phosphate

Reduced to alkanes in Wolff-Kishner process

Ketones

Acyloins

Ketones

Product of Wacker process

Aldehydes

form a silver mirror in Tollens' reagent

Aldehydes

Epoxides

Ethers

Product of Williamson synthesis

Ethers

Claisen rearrangement

Ethers

Aromatic furans

Ethers

Sharpless

Ethers

hydrolyzed to form soaps

Esters

Speier condensation

Esters

Phenyl type in Fries rearrangement

Esters

“beta-keto” type

Esters

Lactone product

Esters

Adding bases = saponification

Esters

Rosenmund Reaction

Carboxyl

volatile derivatives

Carboxyl

second-simplest carboxylic acid

Acetic Acid

“glacial” variety

Acetic Acid

Cativa process

Acetic acid

Monsanto process

Acetic Acid

produce VAM in paints

Acetic Acid

terephthalic acid

Acetic Acid

Lead chamber process

Sulfuric Acid

Contact process

Sulfuric Acid

w/ NaCl in LeBlanc or Mannheim process

Sulfuric Acid

Cycle including vanadium oxide

Sulfuric Acid

Glauber created

Sulfuric Acid

-11.9 Hammett acidity

Sulfuric Acid

“Schlosser” type

Bases

Used in Wolff-Kishner reduction

Bases

Tollens’ reagent

Ammonia

Schweizer’s reagent

Ammonia

Nessler’s solution

Ammonia

Oxidized to hydrazine

Ammonia

Combined in Olin-Raschig process

Ammonia

Magnus’s green salt

Ammonia

Formed in Wittig reaction

Alkenes

Epoxyketones

Alkynes

Installed in Sonogashira reaction

Alkynes

Synthesized in Corey-Fuchs reaction

Alkynes

Metal acetylides

Alkynes

2349 cm IR spectroscopy

Carbon Dioxide

steam reforming

Carbon Monoxide

Heme breakdown produces

Carbon Monoxide

+ Cl = phosgene

Carbon Monoxide

Makes Diels-Alder reaction most efficient

Water

Steam reforming w/ water makes syngas

Methane

Formed in Sabatier process

Methane