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saturated zone
zone where all available pores are filled by water
pressure head in the unsaturated zone
is negative and becomes more negative in drier soils
field capacity
is the water content at which the gravity drainage rate becomes negligible, it defines the “equilibrium of the soil
permanent wilting point
point where plant suction cannot overcome adhesive forces holding water to the soil grains
Available water content
water that is available to plants, difference between field capacity and permanent wilting point
groundwater zone
zone where water content is equal to porosity
Water table line
point where pressure equals atmospheric pressure
tension-saturated zone
zone where pores are filled due to capillary rise, negative pressure
intermediate zone
water content typically at field capacity
root zone
water content may become less than field capacity due to evapotranspiration
Leidenfrost effect
the hot surface creates an insulating vapor layer that prevents the liquid from boiling away rapidly
infiltration
the process by which water arriving at the surface as rain or snowmelt enters the soil
water input rate
rate at which water arrives at the soil surface
infiltration rate
rate at which water enters the soil
infiltration capacity
maximum infiltration rate
no ponding
infiltration rate equals input rate and is less than infiltration capacity
Ponding (saturation from above)
water input rate exceeds infiltration capacity
Ponding (saturation from below)
water table has risen to the surface, infiltration stops
Infiltration rate decreases over time
pores saturate, decreasing pressure head gradient; clay particles swell when wet, reducing pore space; raindrops can wash soil down, clogging pores
wetting front
the downwards movement of water, if it makes it to the water table it can “recharge” groundwater
Groundwater recharge
natural process whereby water enters the saturated zone
without recharge
the natural discharge of groundwater would result in a steadily decreasing water table
groundwater recharge pathways
infiltration/percolation, surface water, artificial
equipotential
an imaginary line (usually drawn on a cross-section or plan view) where all points have the same flow potential (hydraulic head)
we can only reliably draw streamlines between equipotentials if
the aquifer is isotropic and homogeneous
medium is homogeneous
if hydraulic conductivity (K) is the same at all points
medium is isotropic
if Hydraulic conductivity (K) is the same in all directions
groundwater flow systems
can be local, intermediate or regional
groundwater contributes to
baseflow and event flow
event flow
the surge in river flow observed during a rain event
baseflow
is a consistent, slowly varying contribution to the river
groundwater relationship to surface water
lakes, rivers, and wetlands are typically at groundwater discharge points
flow lines must be drawn
perpendicular to equipotentials to predict groundwater flow
hydrograph
a graph showing the rate of flow (discharge) versus time past a specific point in a river
storm hydrograph
plots precipitation and run-off/discharge over time, include baseflow with these
Runoff mechanisms: Channel precipitation
the fastest way for rain to get into the river is to fall directly
Runoff mechanisms: overland flow
rain rate exceeds inflitration rate creating ponding and overflow
Runoff mechanisms: throughflow
is flow through the unsaturated zone, once it breaks surface tension it flows with gravity downslope into the river
Runoff mechanisms: groundwater
a little bit of infiltration into the ground brings the soil up to saturation and allows more groundwater to start flowing
“flash flooding”, fast flow
promoted by steep slopes, sparse vegetation, impervious soil,
different hydrograph shapes
drainage basin conditions are reflected in the hydrograph shape, size, vegetation, slope, soil types
changing hydrograph
land use changes will change the hydrograph shape, removal of vegetation, less permeable surfaces
Unit hydrograph
a tool that allows us to predict the timing and magnitude of peak flow, in response to a precipitation or snow melt event, does not include baseflow
unit hydrograph assumptions 1
two storms with equal duration and equal rainfall excess produce the same hydrograph, regardless of intensity
unit hydrograph assumptions 2
the amount of discharge is assumed to be directly proportional to amount of excess rainfall
unit hydrograph assumptions 3
the timing of runoff is the same, regardless of antecedent conditions
key reasons for constructing a unit hydrograph
flood forecasting and management, extrapolation for various storms, design of hydraulic structures, model ungauged catchments
Volumetric gauging aka Bucket method
only works for very low discharge, directly measures discharge
velocity area method
classic discharge technique, measurements of stream velocity and channel area
challenges of velocity area method
channel geometry is variable, making area estimates tricky, flow velocities can vary significantly
velocity area method drawbacks
doesn’t work well in complex channels, difficult/dangerous in large rivers and during floods, time consuming
Acoustic doppler current profiler (ADCP)
send high frequency sound pulses up (or down) through the water column and reflect off of moving particles
dilution gauging
based on C1V1, dump tracer at some point upstream, time to get downstream point, measure tracer concentration at downstream point
dilution gauging considerations
need to pick an appropriate downstream point
Dilution gauging tracer considerations
readily soluble, zero or low concentration in natural system, inert, easy to detect at low conc, harmless to environment
stage measurement
river stage (or water level/water height) can be monitored easily (and continuously)
stage measurements combined with other measurements
a rating curve can be developed
rating curve
shows the discharge of stream at various stages (depths)
stage measurement drawbacks
if streambed changes its geometry a new rating curve must be developed, it is difficult to get discharged data points for high flow (flood) situations makin the rating curve is unreliable
Weirs
modify river flow so that it travels through a known cross-sectional area with constant velocity
flumes
work similar to weirs but without the sitting pond
weirs/flumes drawbacks
generally only used on small streams, need to be sure all water is flowing through the structure, long-term weir may have sedimentation problems in the stilling pond, may have negative impacts on stream ecology
statistical experiment (or trial)
process or activity in which one outcome from a set of possible outcomes occurs
elementary outcome
each different outcome is known as an “elementary outcome”
sample space
all of the elementary outcomes
event
a subset of the sample space, or a collection of elementary outcomes
return period (recurrence interval or the annual exceedance)
the most common way to describe the probability of a hydrological event
risk
is the probability of at least one flood in a certain number of years
reliability
is the probability of no floods in a certain number of years
flow duration curve
reports how often a river will exceed a certain flow rate
isotopes
different versions of the same element, they contain same number of protons and electrons but different number of neutrons
unstable isotopes
some isotopes don’t like their configuration so they will tend to decay into other products and release energy (radiation)
isotopes of water
water is a combination of hydrogen and oxygen so you could get varying mixtures of these at any time
Isotope standards
Vienna Standard mean ocean water (VSMOW), a deep water collected from different spots around the globe that was mixed, distilled and then analyzed for isotopes
fractionation
any process that changes the isotope ratios
causes of fractionation
thinking of isotopes in terms of heavier and lighter, some travel faster through the water cycle than others,
Light isotopes will
evaporate easier and tend to be consumed first in biological processes
heavier isotopes will
fall faster as precipitation, condense first and form ice easier
isotope “thermometer”
warm places have ratios closer to SMOW but colder places have huge differences, can use isotopes as a “proxy” for temperature
equilibrium fractionation
once water vapour reaches saturation, the relative number of 18O and 2H atoms will also reach a balance, happens because heavier atoms get left in water during evaporation
equilibrium fractionation is
temperature dependent, warmer = less fractionation because warmer water has a better ability to boost heavier atoms out
2H and 18O ratio
is consistently 8:1, 2H depletion is 8 times greater than 18O no matter the temperature
storm tracking with isotopes
there are many different types of precipitation being driven by a warm or cold front resulting in distinct isotopic signatures which can be used to some extent to track storms
tracing groundwater with isotopes
groundwater flow can occur at very different timescales, each timescale has their own isotopic signature
Hydrograph separation with isotopes
following a storm hydrograph we can separate baseflow from event flow based on isotopes which will be different between the two flows
how to measure isotopes
standard is using isotope ratio mass spectroscopy but laser spectrometers are now becoming more common
endmember
a sample of one of the pure, unxed components
tracers
chemical characteristics measured on our endmember
good tracers
should be conservative (non-reactive) and should have contrasting values for the endmembers
we can unmix any number (n) of endmembers but
we need n-1 tracers
dissolved oxygen
the amount of O2 molecules dissolved in water (but not bubbles)
why is dissolved oxygen important
any aquatic creatures that breathe oxygen will be in trouble if DO concentration is low
How is DO measured
usually concentration (mg/L or ppm) or % saturation
why is temperature important
determines solubility of DO, warm water can’t hold very much oxygen
what can go wrong with water temperature
industrial discharge (power plants), low flow + high radiation, and climate change
what is turbidity
a measure fo cloudiness of water, caused by suspended solids and gas bubbles
why is turbidity important
high turbidity makes it difficult for fish/insects to breed, contaminants (including viruses and bacteria) attach themselves to suspended solids
nitrogen compounds
organic nitrogen, ammonia, nitrite, nitrate, fertilizer; measured by titration or spectrophotometry
Why are nitrogen compounds important
it is a critical nutrient for primary production
what can go wrong with Nitrogen compounds
runoff from agriculture land contributes nitrogen to watersheds, excess nitrogen can trigger massive algae blooms