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what does green [Fe(H2O)6]2+ form with NaOH + NH3 in and not in excess?
green Fe(H2O)4(OH)2 precipitate
[Fe(H2O)6]2+ with NaOH in and not in excess equation?
[Fe(H2O)6]2+ + 2OH- → Fe(H2O)4(OH)2 + 2H2O
[Fe(H2O)6]2+ with NH3 in and not in excess equation?
[Fe(H2O)6]2+ + 2NH3 → Fe(H2O)4(OH)2 + 2NH4+
what does green [Fe(H2O)6]2+ form with Na2CO3?
green FeCO3 precipitate with no CO2
[Fe(H2O)6]2+ with Na2CO3 equation?
[Fe(H2O)6]2+ + CO32- → FeCO3 + 6H2O
what does green [Fe(H2O)6]2+ form with HCl?
PALE green FeCl42- solution
[Fe(H2O)6]2+ with HCl equation?
[Fe(H2O)6]2+ + 4Cl- → FeCl42- + 6H2O
what does brown [Fe(H2O)6]3+ solution form with NaOH, NH3 both in and not in excess and Na2CO3?
brown Fe(H2O)3(OH)3 precipitate, CO2 effervescence produced with Na2CO3
[Fe(H2O)6]3+ with NaOH in and not in excess equation?
[Fe(H2O)6]3+ + 3OH- → Fe(H2O)3(OH)3 + 2H2O
[Fe(H2O)6]3+ with NH3 in and not in excess equation?
[Fe(H2O)6]3+ + 3NH3 → Fe(H2O)3(OH)3 + 3NH4+
[Fe(H2O)6]3+ with Na2CO3 equation?
2[Fe(H2O)6]3+ + 3CO32- → 2Fe(H2O)3(OH)3 + 3CO2 + 3H2O
what does brown [Fe(H2O)6]+3 solution produce with HCl?
PALE yellow FeCl4- solution
Fe(H2O)3(OH)3 with HCl equation?
Fe(H2O)3(OH)3 + 4Cl- → FeCl4- + 6H2O
what does blue [Cu(H2O)6]2+ solution produce with NaOH in and not in excess, and NH3?
blue Cu(H2O)4(OH)2 precipitate
[Cu(H2O)6]2+ with NaOH in and not in excess equation?
[Cu(H2O)6]2+ + 2OH- → Cu(H2O)4(OH)2 + 2H2O
[Cu(H2O)6]2+ with NH3 equation?
[Cu(H2O)6]2+ + 2NH3- → Cu(H2O)4(OH)2 + 2NH4+
what does blue [Cu(H2O)6]2+solution form with excess NH3?
DEEP blue Cu(NH3)4(H2O)2 solution
[Cu(H2O)6]2+ with excess NH3 equation?
[Cu(H2O)6]2+ + 4NH3 → Cu(NH3)4(H2O)2 + 2H2O + 2OH-
via ligand sub
what does blue [Cu(H2O)6]2+ solution form with Na2CO3?
green-blue CuCO3 precipitate
[Cu(H2O)6]2+ with Na2CO3 equation?
[Cu(H2O)6]2+ + CO3-2 → CuCO3 + 6H2O
what does blue [Cu(H2O)6]2+ solution form with HCl?
yellow CuCl42- solution
[Cu(H2O)6]2+ with HCl equation?
[Cu(H2O)6]2+ + 4Cl- → CuCl42- + 6H2O
what does colourless [Al(H2O)6]3+ solution produce with NaOH, and how can this be reversed?
white Al(H2O)3(OH)3 precipitate
addition of HCl to precipitate reproduces [Al(H2O)6]3+ as the ion is amphoteric
[Al(H2O)6]3+ with NaOH equation?
[Al(H2O)6]3+ + 3OH- → Al(H2O)3(OH)3 + 3H2O
Al(H2O)3(OH)3 precipitate with HCl equation?
Al(H2O)3(OH)3 + 3H+ → [Al(H2O)6]3+
what does colourless [Al(H2O)6]3+ solution produce with NaOH in excess?
colourless [Al(OH)4]- solution
[Al(H2O)6]3+ with NaOH in excess equation?
[Al(H2O)6]3+ + OH- → [Al(OH)4]- + 3H2O
what does colourless [Al(H2O)6]3+ solution produce with NH3 in excess and Na2CO3?
white Al(H2O)3(OH)3 precipitate, CO2 effervescence produced with Na2CO3
[Al(H2O)6]3+ with excess NH3 equation?
[Al(H2O)6]3+ + 3NH3 → Al(H2O)3(OH)3 + 3NH4+
[Al(H2O)6]3+ with Na2CO3 equation?
2[Al(H2O)6]3+ + 3CO32- → 2Al(H2O)3(OH)3 + 2CO2 + 3H2O