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What happens if resin is not cured all the way?
- Fracture
- Increased wear
- Low bond strength
- Increased micro leakage
Resin based restorative materials belong to the --- family
methacrylate
Methacrylate monomers form polymers via ---
free radical polymerization
What are the steps in free radical polymerization?
Activation
Initiation
Propogation
Termination
How is methacrylate based free radical polymerization activated/initiated.
External energy source = UV light or chemical reaction
Propagation of methacrylate based free radical polymerization
Free radical formed reacts with monomers = forms covalent bond
polymer chain grease longer
What happens as methacrylate based resin chain grows?
Polymer gets stiffer / becomes a solid
How does methacrylate based free radical polymerization terminate?
the 2 free radical chains formed meet and form a covalent bond
What adds strength to free radical polymerization?
Cross linking between chains
Polymers that have little to no cross linking tend to be --- and ---
weak and flexible
What modifies cross linking?
the type of light curing
Benzoyl peroxide
chemical curing agent
True / False: Commonly used terms to describe the output from a curing light such as intensity, power density, or energy density are not SI terms, they are confusing as to what they mean, and ideally they should not be used.
true
The longer the wavelength the --- the frequency
smaller
The shorter the wavelength the --- the frequency
higher
What light is used for light curing today?
Camphorquinone (CQ) = a type of blue light
Factors that affect the ability to polymerize a methacrylate resin based composite
1. depth of cure
2. exposure time
3. thickness of material
4. interaction between light and particles
Degree of conversion
Extent to which resin has been polymerized
depth of cure
Boundary between cured and uncured resin
True / False: As the resin composite thickness increases, exponentially fewer and fewer photons reach to the bottom, thus potentially reducing the degree of conversion of the resin at the bottom
True
The closer the --- of the resin and the filler are matched, the better will be the light transmission through the resin composite and the better the depth of cure
refractive index
Resins become more translucent before or after light curing?
After
If they resin and filler are perfectly matched, the filler particles will optically disappear, but the increased translucency will mean that the resin composite will appear --- In the mouth.
gray
In an un-polymerized state does resin have a higher or lower refractive index compared to the filler particles?
lower
After polymerization does resin have a higher or lower refractive index compared to the filler particles?
higher
True / False: the light source inside the unit can degrade over time and decrease the light output
true
True / False: it is important to use a dental radiometer to routinely measure the output from the curing light.
True
True / False: the light tip can have a significant impact on how much light is delivered to the restoration
true
True / False: the output from curing lights should be tested on the radiometer with the barrier over the light tip
true - barrier reduces light intensity and must be taken into consideration for infection control
True / False: Where the pulp is at greater risk, such as in deep cavities with little overlying dentin, consideration should be given to the choice of LCU and light exposure program. It has been recommended that the tooth should be air-cooled during light exposure from the opposite side.
TRue
Pulpal temperature starts to -- after light exposure
rise
--- tissue damage can be caused by excessive heat from light curing or excessive amounts of light energy delivered to the oral tissues
soft tissue damage
What protects the eyes from blue light?
Orange shields
To maximize the radiant exposure delivered, the light tip should be held both close to and --- to the surface of the restoration
perpendicular