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Solvent
Substance that can dissolve other molecules known as solutes
polar definition
Nuetral/uncharged, but has an asymmetric internal distribution of charge, leading to partially positive and partially negative regions
How does surface tension work
Exposed to air on one side, will have fewer neighboring water molecules to bond with and will form stronger bonds with the neighbors they do have
Why is water less dense as ice
water molecules form a crystal structure maintained by H+ bonds - so water molecules are pushed farther apart than in liquid water
Evaporative cooling
As molecules evaporate, they absorb heat from the surface they evaporate from
What bonds keep Oxygen and Hydrogen in a water molecule together
Polar covalent
What bonds keep two water molecules together
Hydrogen
Electronegative
Affinity for attracting electrons
4 elements common to all living organisms
O, C, H, N
Cations
Positive ions formed by an electron loss
Anions
negative ions formed by electron gain
Polar covalent vs non polar covalent
Polar: electrons shared unequally and closer to one atom
Nonpolar: electrons shared equally
Why are strong and weak bonds necessary in DNA
Strong hold building blocks of DNA strand together, weak hold DNA helix strands together
Dehydration synthesis
polymers formed from monomers. Monomer forms covalent bond to another monomer, releasing a water molecule
Hydrolysis
Monomer formed from polymer. Bond broken by adding water
Carb function
quick/short term energy
Lipid function
long term energy, make up biological membranes
Protein fuctions
Cell structure, send chemical signals, speed up chemical reactions, etc.
What bonds do amino acids form
Covalent
How does the DNA —> RNA —> Protein process work
genes encode sequence of amino acids for particular proteins. RNA copy of gene made (mRNA) which serves as a messenger between DNA and ribosomes (which read mRNA sequence in groups of three (codons) adding amino acid for each codon
tRNA function
Bring amino acids to ribosome for protein synthesis
Nucleotide parts
nitrogenous base (ATCG), 5 carbon sugar, and phosphate group
what does rRNA do
helps mRNA bind in right spot so sequence info can be read out, can also accelerate chemical reactions
What elements does DNA have
Carbon, oxygen, hydrogen, nitrogen, phosphorus
Do proteins have sulfur or phosphorus
Sulfur, no phosphorus
Protein structures
Primary: linear order of amino acids, peptide bonds
Secondary: interactions of the peptide backbones, beta pleated sheets and alpha helices, hydrogen bonds
Tertiary: side chain interactions, 3D, hydrophobic interactions and ionic bonds
Quaternary: multiple peptide chains
Saturated vs unsaturated
Saturated : no double bonds, packed tightly, solid at room temp, can form tighter bonds because there isn’t a link in one leg
Unaturated: double bonds, no tight packing, liquid at room temp, maintain fluidity in membrane
Equation to determine how many water molecules were released during dehydration synthesis
n-1
So if 20 amino acids formed polypeptides, then 19 water molecules were released.
cytosol vs cytoplasm
Cytosol is what is outside of the organelles, cytoplasm refers to what is outside and inside of the cell organelles
if a cell has a lower water potential than the solution it is in, which direction will the water move
Into the cell
Rough ER vs Smooth ER
Rough: protein and lipid synthesis: proteins fold and modify, send to golgi or secreted or incorporated into cell membrane
Smooth: synthesis of carbs, lipids and steroid hormones, detoxifies
Golgi function
Lipids and proteins from ER sorted, packaged, and tagged so they end up in right place.
Lysosome function (only in animal cells)
digestive enzymes and organelle recycling facility - breaks down old/unecessary structures so molecules can be reused, some vesicles that leave the golgi go to lysosome, can digest foreign particles brought into cell (pathogens)
Vacuoles
Storage for water and wastes, isolates hazardous materials and has enzymes that can break down macromolecules, when its full of water it keeps shape of cell
Why is plasma membrane fluid
So things can go in/out and it can rearrange to account for that
Carb function in plasma membrane
Forms distinctive cellular markers that allow cells to recognize each other - important in immune system
Cholesterol function in membrane
minimizes effects of temperature on fluidity
3 factors that affect membrane fluidity
temperature, cholesterol, saturated and unsaturated fatty acids
Which molecules can pass and which cant through the membrane
pass: small non polar (gases), small polar (H20)
need transport protein: large polar(glucose), large non polar(carbon rings), ions (Na+)
Hypertonic vs hypotonic
Hyper: solution has a higher solute concentration than the cell - cell shrinks
Hypo: solution has lower solute concentration than the cell - cell swells
Water potential: ionization constant - when is it -1 and when is it -2
-1 for molecules that don’t dissolve (ex. sugar), -2 for molecules that do dissolve (ex. NaCl)
Light Reaction
Light energy converted into ATP/NADPH using e- from H20
Calvin Cycle (light independent reaction)
Takes newly made ATP to power chem reactions, converting CO2 and H from H20 into glucose
Where does light dependent reactions happen? Calvin Cycle?
Light dependent: thylakoids
Calvin: stroma
light reaction products and reactants
Reactants: light energy, water
Products: ATP, NADHP, oxygen
Photosystem 2 and photosystem 1 function
2: provide energy to create ATP
1: provide energy to create NADPH
Calvin Cycle reactants and products
reactants: co2, ATP, nadph
products: glucose, ADP, NADP
3 phases of Calvin cycle
carbon fixation, reduction, regenerationC
what happens during carbon fixation in Calvin cycle
CO2 is “fixed” into a carb by the enzyme Rubisco
what happens in reduction of calvin cycle
6ATP and 6NADPH used to make 6G3P molecules. ADP and NADP go back to light reactions to be reused and reenergized
What happens in regeneration of Calvin cycle
1 G3P leaves cycle to make glucose, other 5 used to regenerate RuBP so another CO2 can be “fixed” into a carb"
Cellular respiration products and reactants
R: glucose, oxygen
P: CO2, water, ATP
4 steps of cellular respiration
Glycolysis, pyruvate oxidation, Krebs/citric acid cycle, ETC
Where does glycolysis occur
Outside of mitochondria in cytoplasm
What does glycolysis do
Partially oxidizes glucose to 2 pyruvates, gaining 2 ATP and 2 NADH
Why does glycolysis need to break down glucose to pyruvates
To fit through the mitochondrial membrane
2 steps of glycolysis
Energy investment: endergonic, glucose phosphorylated, rearranged, and split into 2 G3P molecules
Energy payoff: Exergonic, G3P gives H to NAD+, G3P broken down into pyruvate
Fermentation (glycolysis without O2)
Keeps glycolysis going by regenerating NAD+, occurs in cytosol, no oxygen needed, produces ATP for energy
Respiration (glycolysis with O2)
Occurs in mitochondria, oxygen required, produces CO2, H2O, and up to 32 ATP
Lactic Acid fermentation
Pyruvate —> lactate , NAD+ is regenerated so glycolysis can occur again which has a net gain of 2 ATP
Pyruvate Oxidation in cellular respiration
Pyruvate enters mitochondrial matrix. Pyruvate —> acetyl CoA
Krebs/citric acid cycle
occurs in mitochondrial matrix, Acetyl CoA —> citrate —> many reactions—>Co2 and NADH and FADH2 released
Net gain: 2 ATP, electron carriers - NADH + FADH2
Where does ETC occur
Along the Cristae in the inner membrane of mitochondria
How does ETC work
H+ ions pumped across inner mitochondrial membrane through protein pumps to create an H+ gradient. At end H+ diffuse through ATP synthase (ADP—> ATP). O2 is final electron acceptor in the form of H2)
Does the inside or outside of mitochondrial matrix have more H+
Outside has more H+