Chapter 18: CHEM 3306 Flashcards
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33 Terms
Previous Aldehyde Synthesis:
Previous Aldehyde Synthesis:
Previous Aldehyde Synthesis:
Previous Aldehyde Synthesis:
Previous Aldehyde Synthesis:
Previous Ketone Synthesis:
Previous Ketone Synthesis:
Previous Ketone Synthesis:
Previous Ketone Synthesis:
Previous Ketone Synthesis:
Imine Synthesis
Enamine Synthesis
Oxime Synthesis
Hydrazone Synthesis
Semicarbezone Synthesis
Hydrate Formation
Hemiacetal Formation
(Hydrolysis) REVERSE Hemiacetal Formation
Acetal Formation (with a Hemiacetal s.m)
(Hydrolysis) REVERSE Acetal Formation (with a Hemiacetal s.m)
Acetal Formation (with a Ketone/Aldehyde s.m)
(Hydrolysis) REVERSE Acetal Formation (with a Ketone/Aldehyde s.m)
Cyclic Acetal Formation: Six-membered ring
Cyclic Acetal Formation: Five-membered ring
Aldehyde and Ketone Protecting Groups
Ylide Formation
Witting Ylide
Witting Reaction
Cyanohydrin Formation
Cyanohydrin Hydrolysis
Nomenclature
Conditions that favor: ACETAL formation
Excess ROH (2 eq.), acid
Anhydrous - NO WATER
Conditions that favor: REVERSE ACETAL (Hydrolysis)
Excess H2O, acid
Dilute aq. acid