Quizbowl Functional Groups/Chemical Compounds I

Reduced to alkanes in Wolff-Kishner process

Ketones

Acyloins

Ketones

Acetone

Ketones

Carbonylated in Cativa process

Alcohols

used to precipitate DNA

Alcohols

“primary” and “secondary” types

Alcohols

Dehydration produces ethers

Alcohols

Hydroboration-oxidation converts alkenes to __

Alcohols

Silyl ethers used to protect

Alcohols

Combined w/ carboxylic acid in Fischer esterification

Alcohols

Grignard reagents + ketones/aldehydes or carbonyls

Alcohols

Formed by opening epoxide

Alcohols

Broad peak at 3300 in IR spec

Alcohols

Forms carboxylic acids/ketones in Jones oxidation

Alcohols

Reacted w/ chromium trioxide dissolved in sulfuric acid

Alcohols

Produced in oxymercuration-reduction

Alcohols

“Sugar” type in artificial sweeteners

Alcohols

“Isopropyl” type

Alcohols

Thiols are sulfur analogues of ___

Alcohols

Reacted w/ pyridinium chlorochromate

Alcohols

OH group

Alcohols

Osmium tetroxide used to add ___

Alcohols

___ + aldehyde = hemiacetal

Alcohols

Most common one causes buildup of formic acid

Alcohols

Forms ethers in Williamson ether synthesis

Alcohols

Ziegler process forms ___

Alcohols

3’ end of DNA molecule defined by ___

Alcohols

Reacted w/ triphenylphosphine

Alcohols

“anti-Markovnikov” type

Alcohols

2-step process w/ mercury (II) acetate

Alcohols

70% concentration __ used in cleaning lab

Alcohols

Forms azeotropes w/ water at 96% concentration

Alcohols

Added asymmetrically using AD-mix

Alcohols

Dess-Martin periodinane

Alcohols

Fleming-Tamao reaction

Alcohols

Lithium aluminum hydride creates ___

Alcohols

DEAD reagent

Alcohols

Product of Barbier reaction

Alcohols

Inverted in Mitsunobu reaction

Alcohols

Formed by addition of organohalides

Alcohols

Formed in Nozaki-Hiyama-Kishi reaction

Alcohols

Product of Wacker process

Aldehydes

form a silver mirror in Tollens' reagent

Aldehydes

Bakelite made from

Aldehydes

Causes cilantro to taste like soap

Aldehydes

Epoxides

Ethers

Product of Williamson synthesis/process

Ethers

Claisen rearrangement

Ethers

Halothane replaced ___ in medicine

Ethers

“Crown” type

Ethers

THF/tetrahydrofuran

Ethers

Alkyl halide + alkoxide = ___

Ethers

Dissolution of alkali metals by ___

Ethers

3,3-sigmatropic rearrangement

Ethers

Byproduct of Blanc chloromethylation

Ethers

“Allyl vinyl” type

Ethers

“Silyl enol” type

Ethers

anisole

Ethers

hydrolyzed to form soaps

Esters

Speier condensation

Esters

Phenyl type in Fries rearrangement

Esters

“beta-keto” type

Esters

Lactone product

Esters

Adding bases = saponification

Esters

Reacted in Claisen condensation

Esters

synthesized from terephthalic acid and ethylene glycol

Esters

Broken down in Kraphco Decarboxylation

Esters

Reduced in Bouveault-Blanc method

Esters

Dieckmann condensation

Esters

Epinephrine synthesized by methylating a __

Amines

Produced by mast cells

Amines

Most common point mutation from hydrolysis of __

Amines

Strecker synthesis

Amino Acids

Ramachandran plot

Amino Acids

fermented by Corynebacterium glutamicum

Amino Acids

herbicide Roundup blocks the synthesis of

Amino Acids

Tryptone is added to LB to feed bacteria

Amino Acids

Impaired in Ames test

Amino Acids

Shikimate pathway

Amino Acids

Urey-Miller experiment created ___

Amino Acids

Hartnup disease affects absorption of ___

Amino Acids

First synthesized by hydrolysis of asparagus juice

Amino Acids

Dihedral angles plotted against residues of ___

Amino Acids

PKU affected by metabolism of ___

Amino Acids

Selenium-hydrogen group

Amino Acids

“Canonical” types

Amino Acids

milky/musty-smelling urine related to ____

Amino Acids

Zwitterions

Amino Acids

Selenol groups

Amino Acids

Neurotransmitter GABA is e.g. of ___

Amino Acids

Rosenmund Reaction

Carboxyls

volatile derivatives

Carboxyls

Aluminum trichloride

Acids

Hammett function

Acids

“Magic” type

Acids

Antimony pentafluoride

Acids

Stabilizes carbocations

Acids

Catalyze electrophilic substitution

Acids

Iron (III) or aluminum (III)

Acids

KHP is standard ___

Acids