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forms of energy
kinetic, potential, thermal, iternal
temperature
a measure related to thermal state
thermodynamic system
any object or region being studied
boundary
imaginary or real surface separating system & surroundings
closed system
energy does not cross boundary
open system
mass and energy can cross boundary
isolated system
no mass or energy transfer
double the size of a system, what happens?
only extensive properties double
a system with temp differences inside
not in equilibrium
a system w/ constant temp but pressure differences
not in equilibrium
temp.. intensive or extensive
intensive
volume… dependent or independent
dependent
property
measurable characteristic of a system
conditions of equilibrium
uniform temp and pressure
if you divide a system into two parts, all properties are halved.. t or f
false
process
a change from one state to another
quasi-static process
process very close to equilibrium at all times
specific volume
volume per unit mass
if mass doubles, specific volume…
stays the same?
physical representation of temp
avg molecular kinetic energy
if density increases, specific volume
decreases
thermodynamic cycle
system returns to initial state
what is greatest form of pressure
absolute pressure
when gauge pressure is 0, abs pressure is
atmospheric pressure
if mass and volume are doubled, specific volume
stays the same
a rod has a steady linear temp gradient. the system
is not in thermal eq
two points at same depth in different-shaped containers. what is pressure difference
pressure is equal
for a closed system what is equation for change in energy
delta E = Q - W
A gas is compressed by a piston. Show work conditions
W<0, work is done on system
two different processes take a system from state 1→2. what stays the same
change in internal energy
work depends on path… true or false
true
heat is stored in a system.. t or f
false
work is a property of a system
false
heat transfer occurs due to…
temperature differences
if Q<0
heat leaves system
heat transfer rate is defined as
Q’ = dQ/dt
conduction occurs due to
molecular collisions
head conduction is dependent on
temperature gradient
convection heat transfer depends on
temp diff
adiabatic process
no heat transfer
delta E = Q - W; t or f
t; change in energy = heat added and work done by system
detla E = W - Q; t or f
false
delta E = W - Q; t or f
false
for a stationary system, what energy changes
KE = PE = 0 change
first law of thermodynamics for a closed system
delta U = Q - W; change in internal energy
change in energy for a complete cycle
delta E = 0
work output of heat engine
W out = Qin - Qout
efficiency
output/input
thermal effcieny is always
less than one
refrigeration cycle main purpose
remove heat from cold space
coefficient of performance
heat removed/work input
why does radiation dominate heat transfer at high temp
radiation depends on T^4
a heat engine has efficiency of 100%
Qo = 0
enthalpy
H = U + pV; enthalpy = internal energy + pressure*volume
at saturation conditions, water exists at
liquid-vapor mixture
if quality x=0, substance is
saturated liquid
for a rigid tank, boundary work is
zero
a rigid tank contains saturated water vapor and is cooled at constant volume. what happens first?
enters two-phase region
water at 150C has quality x = 0.4.. meaning
40% of mass is vapor
which process gives zero bouundary work?
constant volume heating
specific heat Cv represents
energy required to raise temp of unit by mass by one degree at constant volume
for a rigid tank containing closed system, most relevant specific heat is
Cv
for a constant pressure piston cylinder process, heat transfer is most directly related to..
change in enthalpy
specific heat at constant pressure
Cp = (delta h/delta T) p
specific heats are generally defined in
single phase regions only
specific heat ration k is
k = Cp/Cv
an incompressible substance is one whose ____ is approx constant
specific volume
what materials are considered incopressible
liquids and solids
for incompressible substances, internal energy is a function of
temperature only
for incompressible substance w/ constant c, the change in internal energy is
delta u = c(T2-T1)
for incompressible substance, approx enthalpy change is
delta h = c*deltaT + v* deltap
water is heated from 20 to 60 at constant pressure. if incompressible, the main contribution to delta u is…
temp change
why is Cp greater than Cv
constant pressure heating includes expansion work
a block cools from 100 to 40, internal energy…
decreases
liquids are approximated as incompressible.. t or f
true
specific heat is define inside two phase vapor dome.. t or f
false
in rigid tank, boundary work is
zero
if liquid is treated as incompressible,
specific volume is negligible
why is specific heat not define in saturated liquid-vapor mixture region
adding energy may cause phase change wo changing temp
a closed rigid tank of liquid water is heated.. what does say about enthalpy/boundary work
boundary work is approx zero bc volume is constant
internal energy is a state function, t or f
true
heat depends on path, t or f
t
delta U = Q - W, meaning of work and heat, can U be neg
work done by system is pos, heat added to system is pos, if W>Q, then U is neg
adiabatic Q and delta U
Q = 0 and delta U = -W
efficiency = wcycle/Qin, t or f
falset
for a heat engine, how much heat is rejected
some heat is rejected
for a heat engine Qout>Qin, t or f
false
for specific density v = V/m, t or f
true
for specific density, 1/density, t or f
true
specific volume depends on system size t or f
false
gauge pressure can be negative t or f
true
delta U is same for any path btwn two states t or f
true
heat is same for any path t or f
false
if Q>W, delta U <0 t or f
false
if Q = 0, then delta U = -W t or f
true
delta U = Q - W, delta U can be negative t or f
true
a heat engine produces net work t or f
true
A refrigerator consumes workt or f
true
work equals heat rejected t or f
false