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What is a chemical bond?
A mutual electrical attraction between the nuclei and valence electrons of diff atoms that binds the atoms together
Why do atoms bond?
To minimize potential energy and create stability
What is ionic bonding?
Bonding that results from the attraction between large numbers of cations and anions
What happens in ionic bonding?
Atoms completely give up electrons
What are ionic compounds formed between?
Metals and nonmetals
What are types of ionic compounds?
Oxides, salt, hydroxides (OH-)
What is the formula unit?
The simplest collection of atoms from which an ionic compound can be created
What are the types of bonds?
Ionic, metallic, covalent
What are covalent bonds like?
Polar and nonpolar covalent
What is polar covalent?
Unequal sharing e-
One atom that is clearly stronger
What is nonpolar covalent?
Equal sharing of e-
Minimal electronegative differences
What group is unlikely to form an ion?
Group 14
What is the ionic bond shaped like?
Crystalline shape minimizes the potential energy
What forms during ionic bonding?
A crystal lattice because it represents a balance of all attractive and repulsion factors
What are properties of ionic compounds?
Melting point, boiling point, and hardness of the compound depends on how strongly the units attract each other
How strong is an ionic compound's bond?
Strong
What are ionic compounds boiling and melting points like?
They are high boiling and melting points
What is the texture of ionic compounds like?
Hard and brittle
Are ionic compounds soluble and conductive?
Yes and conductive when dissolved in water - can conduct electricity in them well
What is the formation of ionic compounds usually?
Exothermic
What does exothermic mean?
A reaction that releases energy as heat
What is lattice energy?
The energy released when one mole of an ionic crystalline compound is formed
What happens when a value is more negative?
The stronger the attraction is
What does a negative value imply?
Energy is being released
What is lattice energy like for smaller ions?
More negative lattice energy
How does the charge of an ion change attraction?
The greater the charge the more attraction
What are polyatomics?
Atoms that are covalently bonded to one another to form a group of atoms that have both molecular and ionic characteristics
WHat is the metallic bond model not?
Not ionic but forms lattice structures
What do metals have mostly?
Completely vacant p orbitals and d orbitals
What do vacant p and d orbitals allow?
Electrons to roam freely (delocalized) forming a sea of electrons
What do seas of electrons tend to form?
Cations
What are metal's melting points like?
High
What are metals conducttivity like?
Electrical/thermal
What can metals do with light?
Absorb it (luster)
Are metals malleable?
Yes
What does the number of delocalized electrons influence?
Hardness/strength
What are metal alloys easy to?
Introduce other materials into metallic crystal
What is an alloy?
Mixture of elements that have metallic properties
Mostly metals but some nonmetals
What are examples of alloys?
Steel, bronze, brass, aluminum, nichrome, titanium, berrylim-copper, nickel, copper-nickel, niobium
What are the different kinds of alloys?
Subsitution and interstitial
What does covalent compounds and bonding result from?
Sharing of electron pairs between two neutral atoms
Equal
What is the result of covalent compound?
Equal
What is an example of a covalent bond?
Diatomic molecules
What type of covalent are diatomic molecules?
Non-polar covalent
All electrons are shared evenly
What are electrons more attracted to?
The more electronegative atom
What does the electronegativity of the atoms help determine?
Whether atoms will form ionic or covalent bonds
What is the range of two numbers that are nonpolar covalent?
0 - 0.3 (inclusive)
What is the range of two numbers that are polar covalent?
0.3 (exclusive) - 1.7 (inclusive)
What are the numbers that are an ionic bond?
1.7 < #
What is a molecule?
Neutral group of atoms that are held together by covalent compounds
What is a molecular compound?
A chemical compound whose simplest units are molecules
COVALENTLY BONDED
What is a chemical formula?
Shows the relative number of atoms of each kind in a chemical compound by using atomic symbols and numerical subscripts
NaCl
What is a molecular formula?
Shows the types and numbers of atoms combined in a single molecule of a moleacular compound
C6H12O6
What is a diatomic molecule?
A molecule with only two atoms
HOFBrINCl
How do covalent bonds form?
At maximum attraction, the repulsive forces balance the attractive forces
What is bond length?
The distance between the nuclei of bonded atoms at the minimum potential energy
Does a shorter or longer bond release more energy?
Shorter bond
Why does a shorter bond release more energy?
Because there is more energy required to break the bond
What happens when covalent bonds form?
Atoms release energy
What is bond dissociation energy?
The amount of energy required to break the bond
Higher energy = stronger bond
What happens as the number of shared electrons increases?
Bond length decreases - double/triple bonds
How many electrons do single, double, and triple bonds share?
Single = 2e-
Double = 4e-
Triple = 6e-
How are molecular and ionic characteristics similar?
Both molecular (covalent) and ionic bonds are formed for the same reason: to help atoms reach a more stable, lower-energy state
Usually, this means trying to get a full outer shell of electrons (the Octet Rule)
What is electronegativity?
Electronegativity is the ability of an atom to attract shared electrons in a bond
What is negative energy also considered as?
Less energy
What are metallic propeties?
Metallic properties are the physical and chemical characteristics of metals, primarily driven by their ability to easily lose valence electrons (low ionization energy)
What are ionic properties?
Ionic compounds are characterized by high melting and boiling points, crystalline structures, and high solubility in water
What are covalent properties?
Covalent compounds have low melting/boiling points, poor electrical conductivity, and existence as gases, liquids, or soft solids
Why do metallic compounds form?
Metallic forms because the positive atoms cluster together and the electrons float around in the cloud freely among all the atoms
What are covalent bonds between?
Nonmetal and a nonmetal
What are ionic bonds between?
Metal and a nonmetal
Why do crystalline structures form?
Maximizes attraction (opposites close together)
Minimizes repulsion (like charges kept apart)
Lowers energy → more stable
Can alloys be separated?
Yes because its a mixture not a compound