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Order
differentiated based on dominant soil-forming processes
Great Group
based on the strength of soil-forming processes
Subgroups
differentiated based on kind and arrangement of horizons
Families
differentiated based on the basis of the parent material characteristics
Series
differentiated on the basis of detailed features of the pedon
Regosolic Order
-diagnostic feature: no B horizon
-associated with landforms where the land surface is unstable
-soil has little time to develop
Brunisolic Order
-diagnostic horizon: Bm**, Bfj, Btj that are at least 5cm thick, or Bf<10cm thick
-forest soil, not well developed
Luvisolic Order
-diagnostic horizon: Bt
-forest soil in areas with parent material from sedimentary rocks
-eluviation of clay from Ae horizon and deposition into Bt horizon
Gleysolic Order
-diagnostic horizon: Bg (or Cg ≥ 10cm thick within 50cm of soil surface)
-prolonged periods of intermittent or continuous saturation with water
Organic Order
-diagnostic horizons: Of, Om, and Oh must extend to a depth ≥ 40cm
-include peat, bog, and fen soils
-dominant wetland soils in forested regions of Canada, but also occur in non-wetlands in upland sites where leaf litter accumulates
-boreal forest soils
Chernozemic Order
-diagnostic horizon: chernozemic Ah > 10cm thick, Ahe
-grassland soil with high level of organic matter
Solonetzic Order
-diagnostic horizon: Bn or Bnt
-grassland ecosystem
-stinky
-low Ca/Mg ratio
-high levels of Sodium in B horizon
-clay-rich B horizon and saline C horizon
Podzolic Order
-diagnostic horizon: Bf, Bhf, Bh ≥ 10cm thick
-forested soil associated with coniferous vegetation on igneous-rock derived parent materials
-high acidity in A horizon results in Ae horizon with deposits of iron and aluminum in B horizon
Cryosolic Order
-diagnostic horizon: By, Cy, Cz (permafrost)
-arctic and tundra regions
-hard to build on, sensitive soils
Vertisolic Order
-diagnostic horizon: Bss, or Css and Cv
-high clay glacio-lacustrine landscapes
-shrinking and swelling of clays
-poor soil for building and plant growth
A horizon
-mineral horizon near the soil surface
-characterized by eluviation of materials in solution and/or accumulation of organic matter
-most fertile part of the soil profile
Ah
enrichment with organic matter
Ae
eluvial horizon with losses of clay, organic matter, Fe and Al oxides
Ahe
enriched with organic matter but eluviated
B horizon
mineral horizon characterized by illuviation of clay, organic mater, and iron and aluminum oxides, or by in situ weathering
Bm
modified horizon only slightly developed by hydrolysis, oxidation, or solution that is different from adjacent horizons in color, structure, or both
Bt
enriched with silicate clay, usually from Ae horizon above
Bf
enriched with Fe and Al oxides
Bh
enriched with organic matter
Bn
presence of high % of Na ions, with distinct prismatic or columnar structure
Bnt
Na ions and illuvial silicate clay
Bg
gleyed horizon with grey color, mottling, or both as a result of permanent or periodic intense anaerobic conditions
AB
transition between A and B, where A dominates
BA
transition between B and A, where B dominates
C horizon
mineral horizon characterized by little or no alteration through the soil-forming processes operating in the A and B horizons
-usually represents the parent material from which the A and B horizons have formed
Cg
gleyed horizon
Cy
horizon affected by cryoturbation (frost action)
Cz
perennially frozen layer
BC
transition between B and C where C dominates
b
buried horizon
c
cemented irreversibly
ss
presence of several (>2) slickensides
v
affected by agrillipedoturbation (disruption and mixing of soil as a result of shrinking as swelling of clays)
R
rock
W
water
Mor
-matted F horizon
-abrupt boundary between mineral and organic layer
-yes/no H, yes/no Ah
-no clay-humus complex
Moder
-loosely structured F horizon
-more gradual boundary between mineral and organic layer
-yes/no H, yes Ah
-clay-humus complex
-arthropods present in Ah
Mull
-F and H horizons thin or absent
-yes Ah
-no H
-clay-humus complex
-worms and other animals present in Ah
Well-drained conditions
L: litter, well preserved organic structure
F: partly decomposed organic matter, original structures can be hard to recognize
H: accumulation of decomposed organic matter
Poorly-drained conditions
Of: least decomposed, large amounts of well-preserved fibers
Om: intermediate decomposition, mesic
Oh: most decomposed, humic
Heat transfer is due to...
-conduction (through molecular collision)
-convection (by mass movement of molecules)
-radiation (by electromagnetic waves)
Thermal conductivity
describes heat flow in response to a temperature gradient
-higher in mineral layer
-increases as water content increases
Soil heat capacity
represents the amount of heat needed to cause a 1° C change in temperature of a unit volume of soil
-increases with water content
-higher in mineral layer than organic
-water has high heat capacity, air has low heat capacity
Thermal admittance
represents the ability of soil to accept and release heat
-higher in mineral layer than organic
-increases as water content increases
Thermal diffusivity
indication of subsurface temperature response to surface temperature change
Practices that increase admittance and diffusivity...
-adding sand to organic soil
-cultivation
-adding water to dry soil
-removal of organic surface layers
Oxygen flux
the amount of O2 which crosses a plane per unit of time
Diffusive Double Layer (DDL)
occurs where counter ions are attracted to the charged surface of a particle and form a layer
-ions are held by Coulombic forces
-DDL forms under dry conditions
-particles with a thick DDL tend to disperse (high pH)
-particles with a thin DDL tend to flocculate (low pH)
-thickness of DDL depends on concentration of soil solution, valence of attracted ions, and cation size
Neutral soil
pH = 7
H+ and OH- are equally abundant
Acidic soil
pH < 7
more H+ than OH- ions present
Alkaline (basic) soil
pH > 7
more OH- than H+ ions present
Residual acidity
refers to bound H+ and Al3+ that cannot be replaced by unbuffered salt solution
Exchangeable acidity
portion of H+ and Al3+ ions that are absorbed by soil colloids that can be replaced by an unbuffered salt solution such as KCl or NaCl
Active acidity
refers to H+ and Al3+ ions in the salt solution
Consequences of soil salinity
-detrimental effects on plant growth (osmotic potential)
-reduction of water quality
-soil erosion
-damage to infrastructure
-sodic soils --> dispersion, surface sealing, decrease infiltration
Sources of soil acidity
comes from H+ and Al3+ ions in the soil solution and adsorbed to soil colloidal surfaces
Sources of soil basicity
basic soils have a high saturation of base cations (K+, Ca2+, Mg2+, Na+)
Mass ion effect
if many Na+ ions are added, they will likely replace nearly all K+ ions
-as the amount of Na+ ions increases, the probability that Na+ will replace K+ increases
Exchangeable cations
readily displaced by mass ion effect from negatively charged colloids on which they are adsorbed
Cation Exchange Capacity (CEC)
the number of exchangeable cations that soil solids can adsorb
Significance of CEC
-contributes to soil buffering
-contributes to nutrient retention in available forms
-contributes to retention of various contaminants
Base saturation (BS)
fractions of cations on the cation exchange sites occupied by base cations (Ca2+, Mg2+,K+, Na+) rather than H+ and Al3+
Mineralization
the overall process of conversion of an organic form of an element to an inorganic state as a result of microbial decomposition
Immobilization
the conversion of an element from the inorganic to organic form in microbial tissues, thus rendering the element unavailable to plants
Significance of C/N ratio
-residues with a high C/N ratio added to soils --> creates intense competition among microbes and higher plants for available N
-C/N ratio indicates the rate of a residue's decay and the rate at which N is made available to plants
-C/N ratio > 25:1 leads to N deficiency for higher plants
-decay of organic matter is delayed if there's not enough N to support microbial growth
Chelates
organo-mineral complexes in which a metallic ion is bonded to an organic molecule by means of multiple bonds (at least 2), thus forming a ring structure
Organic substances that chelate metals include...
-substances that are synthesized by roots
-various humic substances that have multiple carboxyl groups
-synthetic substances
Dispersed chelates...
contribute to nutrient (metal) availability
Flocculated humic substances...
contribute to nutrient (metal) deficiency
SOM effects on soil physical properties
-dark soil colour
-increases aggregation
-increases water retention
-reduces plasticity and stickiness of clay soils
-improves aeration and drainage
SOM effects on soil chemical properties
-increases CEC
-improves buffering capacity
-provides nutrients (N, S, P)
-chelating agent which can improve nutrient availability (Fe, Zn, Cu, Mn)
Macroorganisms
>2mm in width
Mesoorganisms
0.2-2mm in width
Microorganisms
<0.2mm in width
Rhizosphere
zone of soil influenced by living roots and associated microorganisms
-microorganisms usually feed on the plants and sugars released by roots and sloughed off by cells
-usually extends 1-2mm out of the root surface
Fungi
Kingdom composed of heterotrophs; many obtain energy and nutrients from dead organic matter
Functions:
-aid in decomposition of organic matter
-colonization of plant roots
-killing plants
-biocontrol
Hyphae
The branching, threadlike tubes that make up the bodies of multicellular fungi
Mycelium
network of hyphae
Bacteria
single-celled organisms that lack a nucleus; prokaryotes
Functions:
-N-fixing bacteria make N available to plants
-decompose organic matter and release nutrients in plant-available forms
-convert soil N to gaseous forms
Actinobacteria
filamentous bacteria that:
-decompose soil organic compounds (chitin and cellulose)
-produce antibodies
Archea
single celled prokaryotes, microorganisms
-seen in harsh environments, as well as a broad range of habitats
Protozoa
"primitive animals"
-feed on fungi and bacteria, or fragments of organic matter
-help suppress disease by competing with or feeding on pathogens
-food source for other soil organisms
Nematodes
threadworms
-bacteria feeders --> after consuming bacteria, they excrete much if the excess N as inorganic N (ammonia), which increases nutrient cycling
-predators (biocontrol of insect pests)
-plant parasites (root feeders)
Biological N fixation (transformation of N)
biological conversion of N2 gas to ammonia (NH3) by some bacteria, cyanobacteria, and actinobacteria
-symbiotic N fixers with legumes
Mineralization (transformation of N)
aminization (by heterotrophs)
-ammonification (by heterotrophs)
-nitrification (by chemo-autotrophic bacteria and archea)
Ammonification (transformation of N)
-amines and amino acids are released from the decomposition of proteins, further decomposed by heterotrophic microorganisms
-NH4+ released into the soil is either converted to nitrites or nitrates by nitrification, absorbed by plants, used by heterotrophic microorganisms, absorbed by clay minerals, or released into the atmosphere as elemental N
-R-NH2 + HOH ---> NH3 (ammonia) + R-OH + energy
Sources of Nitrogen
-biological fixation on N
-deposition on N compounds from atmosphere by precipitation
-fertilizers
-organic amendments
-plant residues
Losses of N
-plant removal
-leaching
-wind and water
-ammonium fixation
-gaseous losses (denitrification and NH3 volatilization)
S importance for plants
-protein synthesis
-photosynthesis
-strengthening cell walls
S issues
-atmospheric S deposition
-organic S compounds are not available to plants, microbes need to help
-air, water, and soil pollution with S compounds
P importance for plants
-photosynthesis
-crop maturation
-root development
-strengthening cell walls in grasses
P issues
-total soil P content is low
-solubility of P-containing minerals is low
-soluble P forms (fertilizer) are quickly turned to unavailable forms
Non-humic substances (primary components)
easily decomposed by microorganisms, persist in the soil for a brief time
-carbohydrates, lignin, amino acids, lipids, other compounds
Humic substances (secondary components)
1) fulvic acids
2) humic acids
3) humin
-humic substances possess carboxyl groups, which help buffer pH
-overall change on SOM is negative
Algae
autotrophic, microflora, most active and abundant in wet soils
-make symbiotic associations with fungi, forming lichen
-certain algae secrete polysaccharides, improving soil aggregates