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Chemical equilibrium
Refers to the state of a system in which the concentration of the reactant and the concentration of the products do not change with time
Reactions are reversible
This is indicated by double arrows
Equilibrium
Is the state where the rate of the forward reaction is equal to the rate of the reverse reaction
Gudberg and Waage in 1864
Proposed the general description of the equilibrium, and also known as the law of mass action
Temperature dependent
Equilibrium is ….., how ever it does not change with concentration or pressure
Equilibrium constant expression
What general reaction is this: aA+bB≈cC+dD
Concentration
What does the “{}” mean in the formula
K>1
Favors the products
K<1
Favors the reactants
Pure solid/liquid
Do not appear in expression
Heterogeneous
Weak acid and weak base are what?
Kc
Concentration for aqueous
“K”
Are values that are often written without units
R
Writes the balanced reaction for the predominant reacting species
I
Fills in the initial concentration (must be in molar)
C
Determine the change that is taking in place in terms of x
E
Express the equilibrium concentration in terms of x
Le Chateleir's principle
If a stress is applied to a system at equilibrium, the position of the equilibrium will shift in the direction which reduces stress
consume the added substances
If the concentration increases, the system reacts to
Produce a product
If the concentration decreases, the system reacts to
Shift to the fewest no. Of moles of gas
Increasing pressure results to
Endothermic
Heat is added to the system; heat is reactant
Exothermic
Heat is lost; heat is product