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Absolute zero
The temperature given a value of zero on the Kelvin temperature scale.
Activated complex
Transitional structure that results from an effective collision of reactants
Activation energy
The minimum energy required to transform reactants to activated complex
Atmosphere of pressure
Equivalent exactly to 760 mm of Hg or torr
Boyles law
Volume of a fixed mass of gas varies inversely with the pressure at constant temperature
Calorimeter
A device used to measure the heat absorbed or released in a chemical or physical change
Charles Law
Volume of a fixed mass of gas at constant pressure varies directly with the Kelvin temperature
Combined Gas law
The relationship between pressure, volume, and temperature of a fixed amount of gas
Dalton's Law
The total pressure of a mixture of gases is equal to the sum of partial pressures of component gases
Diffusion
Spontaneous mixing of the particles of two substances caused by random motion
Effusion
Process by which gas particles pass through an opening due to random motion
Endothermic reaction
reaction which the energy of reactants is lower than that of the products at the reaction's completion
Enthalpy change
The amount of energy absorbed or lost by a system during a process at constant pressure.
Exothermic reaction
reaction which the energy of reactants is higher than that of the products at the reaction's completion
Gay Lussac's law
The pressure of a fixed mass of gas at constant volume varies directly with the Kelvin temperature
Heat
Energy transferred between samples of matter because of a difference in temperature.
Heat of reaction
Quantity of energy released or absorbed as heat during a chemical reaction
Ideal gas law
The mathematical relationship of pressure, volume, temperature, and the number of moles of a gas.
Joule
The SI or metric unit of heat energy
Kinetic molecular theory
A theory based upon the idea that particles of matter are always in motion
Law of conservation of energy
Also called the first law of thermodynamics stating energy is neither created nor destroyed it is conserved
Limiting reactant
The reactant controlling the amount of product that can form in a chemical reaction
Pressure
Force per unit area on a surface
Specific heat
Amount of energy required to raise the temperature of 1g of water 1˚ in temperature
STP
Equals zero degrees Celsius and one atmosphere of pressure
Temperature
Measure of the average kinetic energy of particles in a sample of matter
Theoretical yield
Maximum amount of product that can be made from a given amount of reactant
Ideal gas constant
Designated by the letter R it has the value of 0.0821 L ∙atm/mol ∙K
Excessive Reactant
The reactant that is not completely consumed in a chemical reaction