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Oxidation
the loss of one or more electrons from a substance
reduction
the gain of one or more electrons
oxidation and reduction always occur…
together
oxidation in its simplest level,
can also be considered as a reaction in which a substance combines with oxygen (gains oxygen)
reduction in its simplest level,
can also be considered as a reaction in which a substance removes oxygen
oxidation number
a concept that provides a way to keep track of electrons in redox reaction according to certain rules
When combined oxygen always has an oxidation number of +1 except
in H2O2 (-1) and OF2/F2O (+2)
Hydrogen always has an oxidation number of +1 except when
it is part of a metal hydride Ex: NaH, CaH2 (-1)
When an element is oxidized its oxidation number
increases
When an element is reduced its oxidation number
decreases
oxidizing agent
a substance that is able to oxidize other substances (the oxidizing agent itself undergoes reduction)
reducing agent
a substance that is able to reduce other substances (the resting agent itself undergoes oxidation)
voltaic cell
a device used to obtain electrical energy from a spontaneous chemical reaction (also known as ‘galvanic cell”)
Each beaker in a voltaic cell is called a
half-cell
oxidation occurs in the half-cell on the
left side of the diagram
reduction occurs in the half-call on the
right side of the diagram
electrodes:
the solid metals that serve to transfer electrons from one half-cell to another (a conducting wire connects the electrodes)
anode:
the negative electrode in the half-cell where oxidation occurs
cathode:
the positive electrode in the half-cell where reduction occurs
salt bridge:
completes the circuit by preventing the build-up of charge by allowing ions to flow from one solution to another (glass tub fillies with a saturated solution of KNO3 gel)
voltmeter:
measures the potential difference in volts (V).