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exergonic
reactant>product
vicinal
functional group attached to neighboring C
geminal
functional groups attched to same C
endergonic
reactant<product
how many elementary steps for sn1 and e1
2
how many elementary steps for sn2 and e2
1 step (concerted)
how to increase rate of sn2
aprotic solvent
markovnikov
substituent is attached to highest degree C
phenol

benzene

ether
O bound to 2 R
epoxide
O in 3 member ring
how to name epoxide
number largest chain of C
epoxy prefix should have BOTH C # it is attached to
highest bp of alcohol
lowest degree C
>SA
sn1
3 transition states minimum
E2 and SN2
1 transition state
E1
2 transition state
anti-mark mechanisms
hydroboration-oxidation
radical add
simmons smith
syn-dihydroxylation
oxidative cleavage
mark mechanisms
acid-cat hydration and dehydration
ox- merc
ionic add