16.1.2 Reactions of alcs

C__
> alc + O₂ → C__ + __

combustion, CO2, H2O

S__ → h__
w/ HX/P__/PCl₅/S__

substitution, halogenoalkane, PCl3, SOCl2

React w/ N_ → a__ + H₂(g)
> longer C chain = less v__ reaction

Na, alkoxide, vigorous

O__ w/ acidified K__ (dichromate (VI)) OR acidified K__ (manganate (VII)) as o__ agents
> primary alc → a__ + H__ → c__ a__
>> if 1st product desired, it can be d__ (bc b.p. < alc. b.p.)
>> if 2nd product desired, continue under r__ w/ XS o__ agent

> secondary alc → k__ + H__

> tertiary alc → __ __

oxidation, K2Cr2O7, KMnO4, oxidising, aldehyde, H2O, carboxylic acid, distilled, reflux, oxidising, ketone, H2O, no reaction

Oxidation w/ K₂Cr₂O₇
> as this is an o__ agent, itself is r__ thus needs H⁺ from a__
> goes o__ → g__

oxidising, reduced, acid, orange, green

Oxidation w/ KMnO₄
> goes p__ → c__

purple, colourless

D__ (elimination) w/ h__ A__ powder or pumice
> alc. vapour —(A__, h__)→ a__ + H__

dehydration, hot Al2O3, Al2O3, heat, alkene, H2O

E__ (condensation) w/ r__ & s__ a__
> alc. + c__ a__ ←(H__)→ e__ + H₂O

esterification, reflux, strong acid, carboxylic acid, H2SO4, ester