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+q
endothermic
-q
exothermic
heat is added to the system
endothermic (+q)
feels cold (assume beaker)
endothermic (+q)
system gains energy
endothermic (+q)
ice cube melting
endothermic (+q)
cold packs
endothermic (+q)
surroundings are colder
endothermic (+q)
boiling water
endothermic (+q)
heat moves from the system to the surroundings
exothermic (-q)
heat is removed from the system
exothermic (-q)
feels hot (assume beaker)
exothermic (-q)
system loses energy
exothermic (-q)
burning fire
exothermic (-q)
heat goes from the system to the surroundings
exothermic (-q)
surroundings heat up (/get warmer)
exothermic (-q)
freezing water
exothermic (-q)
condensing steam
exothermic (-q)
Calorimetry
Measurement of heat flow
formula for heat
q = Cpm(Tf-Ti)
SI (metric) unit for energy
Joule (J, kilojoule = kJ)
Heat
The energy transferred between two systems at different temperatures that are in contact
Antoine Lavoisier
Father of “heat”
Thermodynamics
The study of energy and its transformations
Temperature
measure of the average motion (KE) of atoms/molecules in a system
temperature is… (intensive/extensive)?
intensive
Zeroth law
Objects that are in thermal equilibrium have the same temperature
First law
Energy cannot be created nor destroyed
q represents..
heat (J)
Cp represents..
specific heat (J/g°C)
m represents..
mass (g)
Tf represents..
the final temperature (°C)
Ti represents…
initial temperature (°C)
(Tf-Ti) can be simplified by..
just taking the change in temperature if stated in the problem
Enthalpy
a measure of the total energy of a thermodynamics system
△H = q
Enthalpy
another unit for heat
1 cal (food is 10³ cal)
heat flows through…..?
molecular collisions
1 J = _ kgm2/s2
1 kgm2/s2
KE = …?
KE = 1/2mv2
Heat Capacity
measures the heat energy required to raise the temperature of an entire object by 1°C (J/°C OR J/K)
Why is specific heat Cp?
C represents the heat, the subscript p tells us its at constant pressure
phase change from solid to liquid
melting —> endothermic
phase change from liquid to gas
vaporization —> endothermic
phase change from gas to liquid
condensation —> exothermic
phase change from liquid to solid
freezing —> exothermic
phase change from solid to gas
sublimation —> endothermic
phase change from gas to solid
deposition —> exothermic