Preparing Alcohols and Diols
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8 Terms
Starting Material | Reagent |
Ketone | BH2/LAH |
Product | Grignard Product |
2º OH | 3º OH |
Starting Material | Reagent |
Aldehyde | BH2/LAH |
Product | Grignard Product |
1º OH | 2º OH |
Starting Material | Reagent |
Ester | Lithium aluminium hydride (LAH) |
Product | Grignard Product |
1º OH | 3º OH |
Starting Material | Reagent |
Carbocyclic Acid | Lithium aluminium hydride (LAH) |
Product | Grignard Product |
1º OH | -Doesn't react because the hydride is more of a base -Grignard is too strong to behave as a nucleophile, it will react as a base |
Reagent | Starting Material |
Chromic Acid | 1º |
Product |
Carboxylic Acid |
Reagent | Starting Material |
Chromic Acid | 2º |
Product |
Ketone |
Reagent | Starting Material |
PCC (weaker than chromic acid) | 1º |
Product |
Aldehyde |
Reagent | Starting Material |
PCC/ Swern / DMP | 2º |
Product |
Ketone |
Note 
Flashcards (20)