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Dalton’s Law of Partial Pressures formula
Pa + Pb + Pn= PT
Mole fraction
Xb= Moles gas/moles total= partial pressure gas/pressure total
Collecting gas over water
Reactions that form gases are collected by bubbling the gas into a container of water. The volume displaced is equal to the volume of the gas. A portion of the gas collected water vapor and not the “dry gas.”
Water pressure varies
By temperature of the water.
Two versions of Dalton’s Law to use when calculating the partial pressure of the dry gas
PT (air pressure) = PH2O (water vapor pressure) + P dry gas
PT-PH2O= P dry gas
Diffusion
Movement of gas molecules from an area of high concentration to low concentration.
Effusion
Diffusion of a gas through a small hole.
Graham’s Law of Effusion
Molecules that are lighter will travel faster, than molecules that are heavier.
Lighter gases have a
Faster rate of effusion.
Heavier gases have a
Slower rate of effusion.
Dalton’s Law states that
The total pressure exerted by the mixture of non-reactive gases is equal to the sum of the partial pressures of individual gases.