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[CH3-CH2]+
29
[H3C-CH2-CH2]+
43
[H3C-CH2-CH2-CH2]+
57
[H2C=CH-CH2]+ (This also may mean that CH3-CH2-CH2 fragment is present)
41
[CH3]+
15
[CH=C-CH2]+ (HC=C-CH2 fragment is present)
39
[H2O]+ (OH present)
18
[CH2=OH]+ (OH-CH2 present)
31
CH3–+C=O
43
[O=C-OH]+
45
CH3O—+C=O
59

Ar+—H
91
[CH2=NH2]+
30

McLafferty cleavage fragments
28 & 44

McLafferty cleavage fragments
28 & 74

McLafferty cleavage fragments
28 & 60

McLafferty cleavage fragments
28 & 59

McLafferty cleavage fragments
28 & 58