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insulator (electrical)
A nonmetallic material that has a filled valence band at 0 K and a relatively wide energy band gap. Consequently, the room-temperature electrical conductivity is very low, less than about 10-10 (Ωm)-1
semiconductor
A nonmetallic material that has a filled valence band at 0 K and a relatively narrow energy band gap. The room-temperature electrical conductivity ranges between about 10-6 and 104 (Ωm)-1
conduction band
For electrical insulators and semiconductors, the lowest-lying electron energy band that is empty of electrons at 0 K. Conduction electrons are those that have been excited to states within this band.
energy band gap
For semiconductors and insulators, the energies that lie between the valence and conduction bands; for intrinsic materials, electrons are forbidden to have energies within this range.
free electron
An electron that has been excited into an energy state above the Fermi energy (or into the conduction band for semiconductors and insulators) and may participate in the electrical conduction process.
hole (electron)
For semiconductors and insulators, a vacant electron state in the valence band that behaves as a positive charge carrier in an electric field.
mobility (electron and hole)
The proportionality constant between the carrier drift velocity and applied electric field; also, a measure of the ease of charge carrier motion.
matthiessen’s rule
The total electrical resistivity of a metal is equal to the sum of temperature-, impurity-, and cold-work-dependent contributions.
intrinsic semiconductor
A semiconductor material for which the electrical behavior is characteristic of the pure material—that is, in which electrical conductivity depends only on temperature and the band gap energy.
extrinsic semiconductor
A semiconducting material for which the electrical behavior is determined by impurities.
donor state (level)
For a semiconductor or insulator, an energy level lying within and near the top of the energy band gap and from which electrons may be excited into the conduction band. It is normally introduced by an impurity atom.
acceptor state (level)
For a semiconductor or insulator, an energy level lying within yet near the bottom of the energy band gap that may accept electrons from the valence band, leaving behind holes. The level is normally introduced by an impurity atom.
doping
The intentional alloying of semiconducting materials with controlled concentrations of donor or acceptor impurities.