AQA A level Chem 3.1 Introduction to Organic Chemistry

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4 Terms

1
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Define the term stereoisomers. (2)

(Different molecules/compounds with the) same (molecular and) structural formula (1)

Different spatial arrangement of atoms (1)

2
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Under suitable conditions, 2-bromobutane reacts with sodium hydroxide to

produce a mixture of five products, A, B, C, D and E.

Products A, B and C are alkenes.

A is a structural isomer of B and C.

A does not exhibit stereoisomerism.

B and C are a pair of stereoisomers.

Products D and E are alcohols.

D and E are a pair of enantiomers.

Deduce the name of isomer A. Explain why A does not exhibit stereoisomerism. (2)

A = but-1-ene (1)

two groups/atoms/Hs the same on one of the C=C carbons (1)

3
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Under suitable conditions, 2-bromobutane reacts with sodium hydroxide to

produce a mixture of five products, A, B, C, D and E.

Products A, B and C are alkenes.

A is a structural isomer of B and C.

A does not exhibit stereoisomerism.

B and C are a pair of stereoisomers.

Products D and E are alcohols.

D and E are a pair of enantiomers.

Deduce the name of isomer B and the name of isomer C. Explain the origin of the stereoisomerism in B and C. (2)

Z-but-2-ene AND E-but-2-ene (1)
lack of/restricted/no (free) rotation around C=C/double bond (1)

4
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