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covalent catalysis
the active site has a reactive group that temporarly covalent bonds to part of the substrate
general acid-base catalysis
a group other than water donates or accepts a proton
metal ion catalysis
metal ions help make nucleophiles stabilize negative changes on intermediates, or bride E to S position the substrate
catalysis by approximation
the enzyme holds two substrates close together on one surface so they react faster
transition-state stabilization
the enzyme binds the transition state even more tightly than the substrate